乙二胺四乙酸铁钠盐制备高氮掺杂多孔碳纳米片氧还原电催化剂

Yong Liu, Tao Wang, Guo Gong, Yong Zhang
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引用次数: 0

摘要

从节能和生态保护的角度来看,燃料电池在储能技术中具有很大的前景。然而,氧还原反应(ORR)总是进行缓慢,导致性能有限。选择优良的ORR电催化剂被认为是一种有效的策略。本文提出了一种制备高氮掺杂多孔碳纳米片(HNPC)电催化剂的简便方法。合成的HNPC电催化剂由于优异的组成特征(高N掺杂)和结构特征(多孔性),通过4e -转移途径获得了极少量HO2 -的优异催化性能。为合成优良的电催化剂提供了一定的指导,对燃料电池的发展具有一定的意义。
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Highly Nitrogen-Doped Porous Carbon Nanosheets Electrocatalyst from Ethylenediaminetetraacetic Acid Ferric Sodium Salt for Oxygen Reduction Reaction
Fuel cells have the great prospect in energy storage technology from the perspective of energy conservation and ecological protection. However, oxygen reduction reaction (ORR) always proceeds sluggishly leads to limited performance. Choosing an excellent ORR electrocatalyst is considered to be an effective strategy. Herein, we have presented an easy synthesis method to prepare highly nitrogen-doped porous carbon nanosheets (HNPC) electrocatalysts. The as-synthesized HNPC electrocatalysts delivered excellent catalytic properties by 4e– transfer pathway with extremely few HO2–, due to excellent compositional characteristics (highly N doping) and structural features (porosity). It provides some guidance for the synthesis of excellent electrocatalysts, which will have certain significance for the development of fuel cells.
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来源期刊
Nanoscience and Nanotechnology Letters
Nanoscience and Nanotechnology Letters Physical, Chemical & Earth Sciences-MATERIALS SCIENCE, MULTIDISCIPLINARY
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