可控组分氢化中四吡啶卟啉的合成

IF 0.8 4区化学 Q4 CHEMISTRY, MULTIDISCIPLINARY Doklady Chemistry Pub Date : 2023-05-23 DOI:10.1134/S0012500823600128

A. V. Lyubimtsev, A. S. Semeikin, M. O. Koifman, O. I. Koifman

{"title":"可控组分氢化中四吡啶卟啉的合成","authors":"A. V. Lyubimtsev, A. S. Semeikin, M. O. Koifman,  O. I. Koifman","doi":"10.1134/S0012500823600128","DOIUrl":null,"url":null,"abstract":"The study focuses on the development of a method of synthesis of a photosensitive mixture of controlled composition containing cationic water-soluble 5,10,15,20-tetrakis(N-Me-pyridin-3-yl)chlorin and 5,10,15,20-tetrakis(N-Me-pyridin-3-yl)bacteriochlorin. The diimide reduction of 5,10,15,20-tetrakis(pyridin-3-yl)porphine in pyridine and in the absence of a solvent has been studied. It has been shown that the reduction in the melt significantly decreases the reaction duration (from 12 to 1.5 h) and affords compositions in up to 90% yield.","PeriodicalId":530,"journal":{"name":"Doklady Chemistry","volume":null,"pages":null},"PeriodicalIF":0.8000,"publicationDate":"2023-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis of Hydrogenated meso-Tetrapyridylporphyrins with a Controlled Composition\",\"authors\":\"A. V. Lyubimtsev, A. S. Semeikin, M. O. Koifman,  O. I. Koifman\",\"doi\":\"10.1134/S0012500823600128\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The study focuses on the development of a method of synthesis of a photosensitive mixture of controlled composition containing cationic water-soluble 5,10,15,20-tetrakis(N-Me-pyridin-3-yl)chlorin and 5,10,15,20-tetrakis(N-Me-pyridin-3-yl)bacteriochlorin. The diimide reduction of 5,10,15,20-tetrakis(pyridin-3-yl)porphine in pyridine and in the absence of a solvent has been studied. It has been shown that the reduction in the melt significantly decreases the reaction duration (from 12 to 1.5 h) and affords compositions in up to 90% yield.\",\"PeriodicalId\":530,\"journal\":{\"name\":\"Doklady Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.8000,\"publicationDate\":\"2023-05-23\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Doklady Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S0012500823600128\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Doklady Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S0012500823600128","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

摘要

研究了一种含有阳离子水溶性5,10,15,20-四(N-Me-pyridin-3-yl)氯和5,10,15,20-四(N-Me-pyridin-3-yl)细菌氯的可控组合物的光敏混合物的合成方法。研究了在吡啶和无溶剂条件下，5,10,15,20-四(吡啶-3-基)卟啉的二亚胺还原反应。研究表明，熔体的减少显著缩短了反应时间(从12小时减少到1.5小时)，并提供了高达90%收率的组合物。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

摘要图片

查看原文

微信好友朋友圈 QQ好友复制链接

本刊更多论文

Synthesis of Hydrogenated meso-Tetrapyridylporphyrins with a Controlled Composition

The study focuses on the development of a method of synthesis of a photosensitive mixture of controlled composition containing cationic water-soluble 5,10,15,20-tetrakis(N-Me-pyridin-3-yl)chlorin and 5,10,15,20-tetrakis(N-Me-pyridin-3-yl)bacteriochlorin. The diimide reduction of 5,10,15,20-tetrakis(pyridin-3-yl)porphine in pyridine and in the absence of a solvent has been studied. It has been shown that the reduction in the melt significantly decreases the reaction duration (from 12 to 1.5 h) and affords compositions in up to 90% yield.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Doklady Chemistry 化学-化学综合

CiteScore

1.20

自引率

12.50%

发文量

审稿时长

6-12 weeks

期刊介绍： Doklady Chemistry is a journal that publishes new research in chemistry and chemical engineering of great significance. Initially the journal was a forum of the Russian Academy of Science and published only best contributions from Russia in the form of short articles. Now the journal welcomes submissions from any country in the English or Russian language. Every manuscript must be recommended by Russian or foreign members of the Russian Academy of Sciences.