1,4-二氧六烷与伯醇二元混合物在303.15 K下的超声、体积和等熵压缩率

S. Agarwal, D. Sharma
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引用次数: 3

摘要

在303.15K的温度下,在整个组成范围内测量了甲醇、乙醇、丙醇、丁醇、己醇和辛醇与1,4-二恶烷的六种二元液体混合物的密度、粘度和声速,计算了粘度偏差(Δη)和等熵压缩性偏差(ΔKS)。这些结果已用于讨论这些混合物中分子间相互作用的性质和强度。
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Ultrasonic, Volumetric and Isentropic Compressibility of Binary Mixtures of 1,4-Dioxane with Primary Alcohols at 303.15 K
Density, viscosity and sound velocity of six binary liquid mixtures of methanol, ethanol, propanol, butanol, hexanol and octanol with 1,4-dioxane have been measured over the entire range of composition at temperature 303.15K. From the experimental densities, viscosities and sound velocity, the excess molar volume (VE), deviation in viscosity (Δη) and deviation in isentropic compressibility (ΔKS) have been calculated. The results have been used to discuss the nature and strength of intermolecular interactions in these mixtures.
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