{"title":"2-苯并噻唑基丙烯酰胺与α-甲基苯乙烯和丙烯酸甲酯的共聚:合成、表征和反应性","authors":"A. Al-Mokaram, Ameen Hadi Mohammed, Hiba A. Ghani","doi":"10.14314/polimery.2022.10.3","DOIUrl":null,"url":null,"abstract":"2-benzothiazolyl acrylamide (BTA) monomer was synthesized by reacting of 2-aminobenzothiazole with acryloyl chloride. Homo- and copolymerization of this monomer with α-methylstyrene (MSt) and methyl acrylate (MA) was carried out in dimethylsulfoxide (DMSO) solution. The prepared homo-and copolymers were characterized by Fourier Transform Infrared (FTIR) and their thermal stability was studied by thermogravimetric analysis (TGA). The composition of copolymers and the reactivity coefficients (r1, r2) were determined on the basis of sulfur analysis using linearization methods proposed by Fineman-Ross and Kelen-Tudos and the Mayo-Lewis intersection method. The derived (r1, r2) for BTA-co-MSt and BTA-co-MA are: (0.197, 0.230) and (0.294, 4.314), respectively. The microstructure of the copolymers and the distribution of the monomer sequences in the copolymers were calculated statistically, the results obtained are consistent with the values (r1, r2). BTA with MSt form alternative copolymer whilst BTA-co-MA tends to be block with MA.","PeriodicalId":20319,"journal":{"name":"Polimery","volume":" ","pages":""},"PeriodicalIF":1.1000,"publicationDate":"2022-11-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Homo- and copolymerization of 2-benzothiazoylacrylamide with α-methyl styrene and methyl acrylate: synthesis, characterization and reactivity\",\"authors\":\"A. Al-Mokaram, Ameen Hadi Mohammed, Hiba A. Ghani\",\"doi\":\"10.14314/polimery.2022.10.3\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"2-benzothiazolyl acrylamide (BTA) monomer was synthesized by reacting of 2-aminobenzothiazole with acryloyl chloride. Homo- and copolymerization of this monomer with α-methylstyrene (MSt) and methyl acrylate (MA) was carried out in dimethylsulfoxide (DMSO) solution. The prepared homo-and copolymers were characterized by Fourier Transform Infrared (FTIR) and their thermal stability was studied by thermogravimetric analysis (TGA). The composition of copolymers and the reactivity coefficients (r1, r2) were determined on the basis of sulfur analysis using linearization methods proposed by Fineman-Ross and Kelen-Tudos and the Mayo-Lewis intersection method. The derived (r1, r2) for BTA-co-MSt and BTA-co-MA are: (0.197, 0.230) and (0.294, 4.314), respectively. The microstructure of the copolymers and the distribution of the monomer sequences in the copolymers were calculated statistically, the results obtained are consistent with the values (r1, r2). BTA with MSt form alternative copolymer whilst BTA-co-MA tends to be block with MA.\",\"PeriodicalId\":20319,\"journal\":{\"name\":\"Polimery\",\"volume\":\" \",\"pages\":\"\"},\"PeriodicalIF\":1.1000,\"publicationDate\":\"2022-11-04\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Polimery\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://doi.org/10.14314/polimery.2022.10.3\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"POLYMER SCIENCE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polimery","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.14314/polimery.2022.10.3","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
Homo- and copolymerization of 2-benzothiazoylacrylamide with α-methyl styrene and methyl acrylate: synthesis, characterization and reactivity
2-benzothiazolyl acrylamide (BTA) monomer was synthesized by reacting of 2-aminobenzothiazole with acryloyl chloride. Homo- and copolymerization of this monomer with α-methylstyrene (MSt) and methyl acrylate (MA) was carried out in dimethylsulfoxide (DMSO) solution. The prepared homo-and copolymers were characterized by Fourier Transform Infrared (FTIR) and their thermal stability was studied by thermogravimetric analysis (TGA). The composition of copolymers and the reactivity coefficients (r1, r2) were determined on the basis of sulfur analysis using linearization methods proposed by Fineman-Ross and Kelen-Tudos and the Mayo-Lewis intersection method. The derived (r1, r2) for BTA-co-MSt and BTA-co-MA are: (0.197, 0.230) and (0.294, 4.314), respectively. The microstructure of the copolymers and the distribution of the monomer sequences in the copolymers were calculated statistically, the results obtained are consistent with the values (r1, r2). BTA with MSt form alternative copolymer whilst BTA-co-MA tends to be block with MA.
期刊介绍:
The "Polimery" journal, of international circulation, is publishing peerreviewed scientific and technical research papers covering polymer science and technology in the field of polymers, rubbers, chemical fibres and paints. The range of topics covered are raw materials, polymer synthesis, processing and applications of polymers. Apart from scientific and technical research papers the monthly includes technical and commercial information such as reports from fairs and exhibitions as well as home, world and technical news.
“Polimery "- an international journal covering the following topics: polymers, rubber, chemical fibres and paints.
The Journal is addressed to scientists, managers and engineering staff of universities, Polish Academy of Sciences, R&D institutions, industry, specializing in polymer chemistry, physical chemistry, technology and processing. “Polimery” publishes original, reviewed research, scientific and technology papers in the field of polymer synthesis, analysis, technology and modification, processing, properties, applications and recycling.