KCl水溶液中热致发光陷阱的结构

Q3 Multidisciplinary Malaysian journal of science Pub Date : 2023-06-30 DOI:10.22452/mjs.vol42no2.9
Ruchi Pandey, Rajendra Kumar, S. Tiwari, S. D. Pandey
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引用次数: 0

摘要

报道了在水性生长的未掺杂KCl晶体中的TL研究结果。对TL曲线进行了五个分量峰的去卷积,并获得了陷阱深度。双空位作为一种基本陷阱的重要性已经得到证实,其阴离子空位末端也被认为是KCl晶体热释光的合适陷阱。还设想了在与杂质空位I-V对相连的阴离子空位处的陷阱,并且陷阱深度的偏移归因于由固有二价离子引起的晶格中I-V对的电场。还发现了一些与羟基相连的陷阱。
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THE STRUCTURE OF THERMOLUMINESCENCE TRAPS IN AQUEOUS GROWN KCl
The results of TL studies in aqueous grown undoped KCl crystals are reported. A de-convolution of TL curve into five component peaks has been performed and trap depths have been obtained. The importance of bi-vacancy has been established as a fundamental trap and its anion vacancy end has also been proposed as a suitable trap for thermoluminescence in KCl crystals. The traps at anion vacancies linked to impurity vacancy I-V pairs have also been envisaged and the shift in the depths of traps is attributed to the electric field of I-V pairs in the lattice caused by inherent divalent ions. Some traps linked to hydroxyl groups have also been identified.
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来源期刊
Malaysian journal of science
Malaysian journal of science Multidisciplinary-Multidisciplinary
CiteScore
1.10
自引率
0.00%
发文量
36
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