用于高性能超级电容器的具有超高比电容和优异循环稳定性的MnO2纳米棒嵌入还原氧化石墨烯纳米复合材料

IF 2.4 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Journal of Molecular and Engineering Materials Pub Date : 2019-10-25 DOI:10.1142/s2251237319500059
M. Sajjad, A. Iqbal, Muhammad Ibrar Khan, M. Qureshi, Y. Khan
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引用次数: 7

摘要

优异的循环稳定性以及电极材料的高比电容是近年来对超级电容器(SC)的主要要求。首次采用异常简单且具有成本效益的溶液工艺制备[式:见正文]-MnO2/rGO复合材料,其中KMnO4含量从(2[式:参见正文]mg、4[式:详见正文]mg,6[式:请见正文]mg和8[式:参阅正文]mg)变化。形态分析表明,[式:见正文]-MnO2/rGO复合材料具有纳米棒状形态,并被rGO片完全覆盖。在所有复合材料中,具有6[式:见正文]mg KMnO4含量的样品(表示为[式:参见正文]-MnO2/rGO复合材料(S–3))在4 a g的电流密度下显示出优异的超级电容性能,比电容为720[式:详见正文]F/g[式:请见正文],2000次循环后具有93%的优异循环稳定性。此外,这些纳米复合材料显示出优异的超级电容性能,在4 A g的电流密度下,比电容为720–498 F/g[公式:见正文],循环稳定性分别为71%、68%和60%。
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MnO2 Nanorods Embedded Reduced Graphene Oxide Nanocomposite with Ultrahigh Specific Capacitance and Excellent Cyclic Stability for High Performance Supercapacitors
Excellent cycling stability along with a high specific capacitance of the electrode material is the primary requirement for supercapacitor (SC) in recent years. Exceptionally simple and cost-effective solution process is employed for the first time to prepare [Formula: see text]-MnO2/rGO composites, in which KMnO4 content varies from (2[Formula: see text]mg, 4[Formula: see text]mg, 6[Formula: see text]mg and 8[Formula: see text]mg). The morphological analysis showed that [Formula: see text]-MnO2/rGO composites possess nanorod like morphology and were fully covered with rGO sheet. Among all composites, the sample with 6[Formula: see text]mg content of KMnO4 denoted as [Formula: see text]-MnO2/rGO composite (S–3) showed excellent supercapacitive performance with a specific capacitance of 720[Formula: see text]F/g at a current density of 4 A g[Formula: see text] with excellent cycling stability of 93% after 2000 cycles. Furthermore, these nanocomposites showed excellent supercapacitive properties with specific capacitances of 720–498 F/g at the current density of 4 A g[Formula: see text] with cycling stabilities of 71%, 68% and 60%, respectively.
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Journal of Molecular and Engineering Materials
Journal of Molecular and Engineering Materials MATERIALS SCIENCE, MULTIDISCIPLINARY-
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