{"title":"沸石催化剂酸碱特性对丙烷二氧化碳氧化脱氢反应的影响","authors":"A. Yu. Kapran, S. M. Orlyk","doi":"10.1007/s11237-022-09729-2","DOIUrl":null,"url":null,"abstract":"<div><div><p>The peculiarities of propane dehydrogenation with carbon dioxide over zeolite catalysts of different structural types, in particular, BEA with incorporated Zn, Ga (Ta, Nb) heteroelements have been analyzed. The role of CO<sub>2</sub> as an oxidant, the effect of acid–base characteristics on propylene selectivity and yield, the stability of catalyst operation, and the routes of activation of reagents on acid–base sites of the surface are considered.</p></div></div>","PeriodicalId":796,"journal":{"name":"Theoretical and Experimental Chemistry","volume":"58 2","pages":"118 - 129"},"PeriodicalIF":0.7000,"publicationDate":"2022-08-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Effect of Acid–Base Characteristics of Zeolite Catalysts on Oxidative Dehydrogenation of Propane with Carbon Dioxide\",\"authors\":\"A. Yu. Kapran, S. M. Orlyk\",\"doi\":\"10.1007/s11237-022-09729-2\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div><p>The peculiarities of propane dehydrogenation with carbon dioxide over zeolite catalysts of different structural types, in particular, BEA with incorporated Zn, Ga (Ta, Nb) heteroelements have been analyzed. The role of CO<sub>2</sub> as an oxidant, the effect of acid–base characteristics on propylene selectivity and yield, the stability of catalyst operation, and the routes of activation of reagents on acid–base sites of the surface are considered.</p></div></div>\",\"PeriodicalId\":796,\"journal\":{\"name\":\"Theoretical and Experimental Chemistry\",\"volume\":\"58 2\",\"pages\":\"118 - 129\"},\"PeriodicalIF\":0.7000,\"publicationDate\":\"2022-08-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Theoretical and Experimental Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11237-022-09729-2\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Theoretical and Experimental Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s11237-022-09729-2","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Effect of Acid–Base Characteristics of Zeolite Catalysts on Oxidative Dehydrogenation of Propane with Carbon Dioxide
The peculiarities of propane dehydrogenation with carbon dioxide over zeolite catalysts of different structural types, in particular, BEA with incorporated Zn, Ga (Ta, Nb) heteroelements have been analyzed. The role of CO2 as an oxidant, the effect of acid–base characteristics on propylene selectivity and yield, the stability of catalyst operation, and the routes of activation of reagents on acid–base sites of the surface are considered.
期刊介绍：
Theoretical and Experimental Chemistry is a journal for the rapid publication of research communications and reviews on modern problems of physical chemistry such as:
a) physicochemical bases, principles, and methods for creation of novel processes, compounds, and materials;
b) physicochemical principles of chemical process control, influence of external physical forces on chemical reactions;
c) physical nanochemistry, nanostructures and nanomaterials, functional nanomaterials, size-dependent properties of materials.
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