过滤浸渍用煤基多孔石墨的分形及渗透特性研究

IF 5.8 4区 工程技术 Q1 MECHANICS Applied Rheology Pub Date : 2023-01-01 DOI:10.1515/arh-2022-0157
Qili Wang, J. Wang, Shuwei Yang, Jiarui Sun
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引用次数: 0

摘要

摘要为了区分多孔石墨在过滤和浸渍过程中所采用的非均匀分形结构的差异,根据分形理论,采用压汞孔隙率计(MIP)获得了分形维数,计算了10个石墨样品的体积分形维数。对弯曲度的FD表达式以及MIP测试的所有参数进行了优化,以简化计算。此外,根据实验数据,分析了汞在多孔介质中的渗流演化过程。根据所进行的分析,样品骨架形成区域的FD在2.695至2.984之间变化,渗透区域的FD为2.923至2.991,曲折度为1.224至1.544。基于范围在0.906和0.999之间的相关系数(R2)({R}^{2}),以及范围在0.0001和0.0065之间的均方根误差 mL g−1,确定了高水平的可靠性。根据MIP测试,汞在多孔石墨中的分布表现出从局部聚集、逐渐膨胀、无限团簇连接到全局连接的过渡过程。
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A study on the fractal and permeability characteristics of coal-based porous graphite for filtration and impregnation
Abstract In order to distinguish the differences in the heterogeneous fractal structure of porous graphite adopted in the filtration and impregnation, the fractal dimensions (FDs) were obtained by the mercury intrusion porosimetry (MIP) to calculate the volumetric FDs of ten graphite samples, following the fractal theory. The FD expression of the tortuosity along with all the parameters from the MIP test was optimized to simplify the calculation. In addition, the percolation evolution process of mercury in the porous media was analyzed based on the data collected in the experiment. According to the analysis conducted, the FDs in the backbone formation regions of samples varied from 2.695 to 2.984, with 2.923 to 2.991 in the percolation regions and 1.224 to 1.544 in the tortuosity. Based on the correlation coefficients ( R 2 ) ({R}^{2}) ranging between 0.906 and 0.999, and the root mean square errors ranging between 0.0001 and 0.0065 mL g−1, a high level of reliability was identified. According to the MIP test, the mercury distribution in porous graphite demonstrated a transitional process from the local aggregation, the gradual expansion, the infinite cluster connection to the global connection.
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来源期刊
Applied Rheology
Applied Rheology 物理-力学
CiteScore
3.00
自引率
5.60%
发文量
7
审稿时长
>12 weeks
期刊介绍: Applied Rheology is a peer-reviewed, open access, electronic journal devoted to the publication in the field of applied rheology. The journal provides the readers with free, instant, and permanent access to all content worldwide; and the authors with extensive promotion of published articles, long-time preservation, language-correction services, no space constraints and immediate publication.
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