酒石酸锑二聚体的层状结构

IF 0.9 4区材料科学 Q3 CRYSTALLOGRAPHY Zeitschrift Fur Kristallographie-Crystalline Materials Pub Date : 2022-07-11 DOI:10.1515/zkri-2022-0033

Xiqu Wang, A. Jacobson

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引用次数: 0

摘要

摘要通过缓慢蒸发酒石酸锑钾和金属硝酸盐或氯化物的水溶液，合成了四种单晶形式的复合金属酒石酸锑。这些化合物的晶体结构都包含通过将酒石酸锑二聚体与M=Li、La、Ce或Nd的M–O键连接而形成的无限层。La和Ce化合物在高温下的脱水通过单晶到单晶的转变产生了新的层状结构。

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Layered structures based on antimony tartrate dimers

Abstract Four complex metal antimony tartrates have been synthesized in single crystal form by slowly evaporating aqueous solutions of potassium antimony tartrate (tartar emetic) and metal nitrates or chlorides. Crystal structures of these compounds all contain infinite layers formed by linking antimony tartrate dimers with M–O bonds, with M = Li, La, Ce or Nd. Dehydration of the La and Ce compounds at elevated temperatures led to new layered structures via single-crystal to single-crystal transformations.

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来源期刊

Zeitschrift Fur Kristallographie-Crystalline Materials CRYSTALLOGRAPHY-

CiteScore

2.00

自引率

16.70%

发文量

期刊介绍： Zeitschrift für Kristallographie – Crystalline Materials was founded in 1877 by Paul von Groth and is today one of the world’s oldest scientific journals. It offers a place for researchers to present results of their theoretical experimental crystallographic studies. The journal presents significant results on structures and on properties of organic/inorganic substances with crystalline character, periodically ordered, modulated or quasicrystalline on static and dynamic phenomena applying the various methods of diffraction, spectroscopy and microscopy.