Si Ke , Duanyi Zhang , Yu Li , Ziwei Gong , Pengcheng Tang , Wanxia Tang
{"title":"新型丁香醛α-氨基膦酸衍生物的一锅合成及其荧光性质","authors":"Si Ke , Duanyi Zhang , Yu Li , Ziwei Gong , Pengcheng Tang , Wanxia Tang","doi":"10.1080/10426507.2023.2187798","DOIUrl":null,"url":null,"abstract":"<div><p>Seven novel syringaldehyde α-aminophosphonate derivatives (<strong>1</strong>–<strong>7</strong>) were synthesized based on syringaldehyde together with different aryl amines and diethyl phosphite in a one-pot, solvent free, and catalyst free reaction. All of the obtained compounds were characterized by analysis of their <sup>1</sup>H NMR and <sup>13</sup>C NMR, IR spectra, and FT mass spectra. The UV and fluorescence emission spectra of <strong>1</strong>–<strong>7</strong> were investigated in the concentration range of 0.1–250 μM. As the results, the maximum emission wavelength of <strong>1</strong>–<strong>7</strong> was observed between 600 and 700<!--> <!-->nm under the exciting wavelength of 250<!--> <!-->nm for <strong>1</strong>–<strong>5</strong> and 300<!--> <!-->nm for <strong>6</strong> and <strong>7</strong>. The emission intensity is the strongest at a concentration of 60<!--> <!-->μm for <strong>2</strong>, <strong>3</strong>, and <strong>5</strong>–<strong>7</strong>, 30<!--> <!-->μm for <strong>1</strong>, and 0.1<!--> <!-->μm for <strong>4</strong>.</p></div>","PeriodicalId":20056,"journal":{"name":"Phosphorus, Sulfur, and Silicon and the Related Elements","volume":null,"pages":null},"PeriodicalIF":1.4000,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"One-pot synthesis and fluorescent property of novel syringaldehyde α-aminophosphonate derivatives\",\"authors\":\"Si Ke , Duanyi Zhang , Yu Li , Ziwei Gong , Pengcheng Tang , Wanxia Tang\",\"doi\":\"10.1080/10426507.2023.2187798\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Seven novel syringaldehyde α-aminophosphonate derivatives (<strong>1</strong>–<strong>7</strong>) were synthesized based on syringaldehyde together with different aryl amines and diethyl phosphite in a one-pot, solvent free, and catalyst free reaction. All of the obtained compounds were characterized by analysis of their <sup>1</sup>H NMR and <sup>13</sup>C NMR, IR spectra, and FT mass spectra. The UV and fluorescence emission spectra of <strong>1</strong>–<strong>7</strong> were investigated in the concentration range of 0.1–250 μM. As the results, the maximum emission wavelength of <strong>1</strong>–<strong>7</strong> was observed between 600 and 700<!--> <!-->nm under the exciting wavelength of 250<!--> <!-->nm for <strong>1</strong>–<strong>5</strong> and 300<!--> <!-->nm for <strong>6</strong> and <strong>7</strong>. The emission intensity is the strongest at a concentration of 60<!--> <!-->μm for <strong>2</strong>, <strong>3</strong>, and <strong>5</strong>–<strong>7</strong>, 30<!--> <!-->μm for <strong>1</strong>, and 0.1<!--> <!-->μm for <strong>4</strong>.</p></div>\",\"PeriodicalId\":20056,\"journal\":{\"name\":\"Phosphorus, Sulfur, and Silicon and the Related Elements\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.4000,\"publicationDate\":\"2023-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Phosphorus, Sulfur, and Silicon and the Related Elements\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S1042650723000278\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Phosphorus, Sulfur, and Silicon and the Related Elements","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1042650723000278","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
One-pot synthesis and fluorescent property of novel syringaldehyde α-aminophosphonate derivatives
Seven novel syringaldehyde α-aminophosphonate derivatives (1–7) were synthesized based on syringaldehyde together with different aryl amines and diethyl phosphite in a one-pot, solvent free, and catalyst free reaction. All of the obtained compounds were characterized by analysis of their 1H NMR and 13C NMR, IR spectra, and FT mass spectra. The UV and fluorescence emission spectra of 1–7 were investigated in the concentration range of 0.1–250 μM. As the results, the maximum emission wavelength of 1–7 was observed between 600 and 700 nm under the exciting wavelength of 250 nm for 1–5 and 300 nm for 6 and 7. The emission intensity is the strongest at a concentration of 60 μm for 2, 3, and 5–7, 30 μm for 1, and 0.1 μm for 4.
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Phosphorus, Sulfur, and Silicon and the Related Elements is a monthly publication intended to disseminate current trends and novel methods to those working in the broad and interdisciplinary field of heteroatom chemistry.
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