Dr. Caterina Damiano, Matteo Cavalleri, Prof. Corrado di Natale', Prof. Roberto Paolesse, Prof. Emma Gallo
{"title":"固定在彩色捕集器®上的卟啉:用于将胺转化为亚胺和将醛转化为羧酸的光活性材料","authors":"Dr. Caterina Damiano, Matteo Cavalleri, Prof. Corrado di Natale', Prof. Roberto Paolesse, Prof. Emma Gallo","doi":"10.1002/ceur.202300020","DOIUrl":null,"url":null,"abstract":"<p>A new photoactive material was obtained by the heterogenization of zinc(II) porphyrin onto cellulose-based Colour Catcher® sheet. The so-obtained Zn(porphyrin)@CC material performed very well in activating molecular oxygen in the photooxidative coupling of amines to imines and the photooxidation of aldehydes to corresponding acids in the presence of white light. The high eco-compatibility of the solid support, the chemical stability of the photoactive material and the mild experimental conditions applied confer a very good sustainability to the procedure and open the doors to a larger employment of Colour Catcher®-based porphyrin material in reactions mediated by light.</p>","PeriodicalId":100234,"journal":{"name":"ChemistryEurope","volume":"1 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2023-05-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ceur.202300020","citationCount":"0","resultStr":"{\"title\":\"Porphyrins Anchored onto Colour Catcher®: Photoactive Material for the Conversion of Amines into Imines and Aldehydes into Carboxylic Acids\",\"authors\":\"Dr. Caterina Damiano, Matteo Cavalleri, Prof. Corrado di Natale', Prof. Roberto Paolesse, Prof. Emma Gallo\",\"doi\":\"10.1002/ceur.202300020\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>A new photoactive material was obtained by the heterogenization of zinc(II) porphyrin onto cellulose-based Colour Catcher® sheet. The so-obtained Zn(porphyrin)@CC material performed very well in activating molecular oxygen in the photooxidative coupling of amines to imines and the photooxidation of aldehydes to corresponding acids in the presence of white light. The high eco-compatibility of the solid support, the chemical stability of the photoactive material and the mild experimental conditions applied confer a very good sustainability to the procedure and open the doors to a larger employment of Colour Catcher®-based porphyrin material in reactions mediated by light.</p>\",\"PeriodicalId\":100234,\"journal\":{\"name\":\"ChemistryEurope\",\"volume\":\"1 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2023-05-05\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ceur.202300020\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ChemistryEurope\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/ceur.202300020\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ChemistryEurope","FirstCategoryId":"1085","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/ceur.202300020","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Porphyrins Anchored onto Colour Catcher®: Photoactive Material for the Conversion of Amines into Imines and Aldehydes into Carboxylic Acids
A new photoactive material was obtained by the heterogenization of zinc(II) porphyrin onto cellulose-based Colour Catcher® sheet. The so-obtained Zn(porphyrin)@CC material performed very well in activating molecular oxygen in the photooxidative coupling of amines to imines and the photooxidation of aldehydes to corresponding acids in the presence of white light. The high eco-compatibility of the solid support, the chemical stability of the photoactive material and the mild experimental conditions applied confer a very good sustainability to the procedure and open the doors to a larger employment of Colour Catcher®-based porphyrin material in reactions mediated by light.