一种抑制有机荧光染料光漂白的高效可逆单态氧猝灭剂

IF 3.4 Q2 CHEMISTRY, ANALYTICAL Analysis & sensing Pub Date : 2022-12-08 DOI:10.1002/anse.202200099
Rui Jiang, En-lai Yang, Zhen-zhen Lin, Prof. Xu-dong Wang
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引用次数: 0

摘要

猝灭单线态氧是提高荧光染料光稳定性的关键。我们系统地研究了一种新的单线态氧猝灭剂DABCOnium(1,4-二氮杂双环[2.2.2]辛烷的烷基化衍生物)去除单线态氧的能力。结果表明,DABCOnium能显著提高荧光薄膜的光稳定性4.3以上 与没有DABCOnium的情况相比。2之后 连续照射小时,掺有DABCOnium的荧光膜保留90 % 这为设计高性能单线态氧猝灭剂开辟了一条新的途径。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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An Efficient and Reversible Singlet Oxygen Quencher for Suppressing Photobleaching of Organic Fluorescent Dyes

Quenching singlet oxygen is the key to improve photostability of fluorescent dyes. We have systematically studied the capability of a new singlet oxygen quencher, DABCOnium (an alkylated derivative of 1,4-diazabicyclo[2.2.2] octane) on removing singlet oxygen. Results showed that DABCOnium can significantly enhancing photostability of fluorescent thin films for more than 4.3 times compared with that without DABCOnium. After 2 hours of continuous irradiation, fluorescent film doped with DABCOnium retained 90 % of its original fluorescence intensity, which paves a new way in designing high performance singlet oxygen quenchers.

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