V. O. Zozulia, K. V. Terebilenko, S. G. Nedilko, V. P. Chornii, M. S. Slobodyanik
{"title":"K2Bi(PO4)(MoO4):Gd,Eu固溶体的发光特性","authors":"V. O. Zozulia, K. V. Terebilenko, S. G. Nedilko, V. P. Chornii, M. S. Slobodyanik","doi":"10.1007/s11237-023-09769-2","DOIUrl":null,"url":null,"abstract":"<div><div><p>Solid solutions K<sub>2</sub>Bi(PO<sub>4</sub>)(MoO<sub>4</sub>):Gd,Eu containing from 0.1 to 30 mole% of europium(III) and 0.1 mole% of gadolinium(III) have been prepared by conventional solid state reaction. The samples are characterized by X-ray powder diffraction method, IR and luminescence spectroscopies. It has been shown that doping with Eu<sup>3+</sup> does not affect the symmetry of the layered framework. At room temperature, all the studied samples are characterized by intense red photoluminescence, which is associated with <sup>5</sup><i>D</i><sub>0</sub>→<sup>7</sup><i>F</i><sub>0-4</sub> emission transitions in Eu<sup>3+</sup> ions. Due to the absence of concentration quenching and color characteristics, K<sub>2</sub>Bi(PO<sub>4</sub>)(MoO<sub>4</sub>):Gd,Eu has prominent prospects for application as a red phosphor.</p></div></div>","PeriodicalId":796,"journal":{"name":"Theoretical and Experimental Chemistry","volume":null,"pages":null},"PeriodicalIF":0.7000,"publicationDate":"2023-07-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Luminescence Properties of K2Bi(PO4)(MoO4):Gd,Eu Solid Solutions\",\"authors\":\"V. O. Zozulia, K. V. Terebilenko, S. G. Nedilko, V. P. Chornii, M. S. Slobodyanik\",\"doi\":\"10.1007/s11237-023-09769-2\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div><p>Solid solutions K<sub>2</sub>Bi(PO<sub>4</sub>)(MoO<sub>4</sub>):Gd,Eu containing from 0.1 to 30 mole% of europium(III) and 0.1 mole% of gadolinium(III) have been prepared by conventional solid state reaction. The samples are characterized by X-ray powder diffraction method, IR and luminescence spectroscopies. It has been shown that doping with Eu<sup>3+</sup> does not affect the symmetry of the layered framework. At room temperature, all the studied samples are characterized by intense red photoluminescence, which is associated with <sup>5</sup><i>D</i><sub>0</sub>→<sup>7</sup><i>F</i><sub>0-4</sub> emission transitions in Eu<sup>3+</sup> ions. Due to the absence of concentration quenching and color characteristics, K<sub>2</sub>Bi(PO<sub>4</sub>)(MoO<sub>4</sub>):Gd,Eu has prominent prospects for application as a red phosphor.</p></div></div>\",\"PeriodicalId\":796,\"journal\":{\"name\":\"Theoretical and Experimental Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.7000,\"publicationDate\":\"2023-07-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Theoretical and Experimental Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11237-023-09769-2\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Theoretical and Experimental Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s11237-023-09769-2","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Luminescence Properties of K2Bi(PO4)(MoO4):Gd,Eu Solid Solutions
Solid solutions K2Bi(PO4)(MoO4):Gd,Eu containing from 0.1 to 30 mole% of europium(III) and 0.1 mole% of gadolinium(III) have been prepared by conventional solid state reaction. The samples are characterized by X-ray powder diffraction method, IR and luminescence spectroscopies. It has been shown that doping with Eu3+ does not affect the symmetry of the layered framework. At room temperature, all the studied samples are characterized by intense red photoluminescence, which is associated with 5D0→7F0-4 emission transitions in Eu3+ ions. Due to the absence of concentration quenching and color characteristics, K2Bi(PO4)(MoO4):Gd,Eu has prominent prospects for application as a red phosphor.
期刊介绍:
Theoretical and Experimental Chemistry is a journal for the rapid publication of research communications and reviews on modern problems of physical chemistry such as:
a) physicochemical bases, principles, and methods for creation of novel processes, compounds, and materials;
b) physicochemical principles of chemical process control, influence of external physical forces on chemical reactions;
c) physical nanochemistry, nanostructures and nanomaterials, functional nanomaterials, size-dependent properties of materials.