K2Bi(PO4)(MoO4):Gd,Eu固溶体的发光特性

IF 0.7 4区 化学 Q4 CHEMISTRY, MULTIDISCIPLINARY Theoretical and Experimental Chemistry Pub Date : 2023-07-28 DOI:10.1007/s11237-023-09769-2
V. O. Zozulia, K. V. Terebilenko, S. G. Nedilko, V. P. Chornii, M. S. Slobodyanik
{"title":"K2Bi(PO4)(MoO4):Gd,Eu固溶体的发光特性","authors":"V. O. Zozulia,&nbsp;K. V. Terebilenko,&nbsp;S. G. Nedilko,&nbsp;V. P. Chornii,&nbsp;M. S. Slobodyanik","doi":"10.1007/s11237-023-09769-2","DOIUrl":null,"url":null,"abstract":"<div><div><p>Solid solutions K<sub>2</sub>Bi(PO<sub>4</sub>)(MoO<sub>4</sub>):Gd,Eu containing from 0.1 to 30 mole% of europium(III) and 0.1 mole% of gadolinium(III) have been prepared by conventional solid state reaction. The samples are characterized by X-ray powder diffraction method, IR and luminescence spectroscopies. It has been shown that doping with Eu<sup>3+</sup> does not affect the symmetry of the layered framework. At room temperature, all the studied samples are characterized by intense red photoluminescence, which is associated with <sup>5</sup><i>D</i><sub>0</sub>→<sup>7</sup><i>F</i><sub>0-4</sub> emission transitions in Eu<sup>3+</sup> ions. Due to the absence of concentration quenching and color characteristics, K<sub>2</sub>Bi(PO<sub>4</sub>)(MoO<sub>4</sub>):Gd,Eu has prominent prospects for application as a red phosphor.</p></div></div>","PeriodicalId":796,"journal":{"name":"Theoretical and Experimental Chemistry","volume":null,"pages":null},"PeriodicalIF":0.7000,"publicationDate":"2023-07-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Luminescence Properties of K2Bi(PO4)(MoO4):Gd,Eu Solid Solutions\",\"authors\":\"V. O. Zozulia,&nbsp;K. V. Terebilenko,&nbsp;S. G. Nedilko,&nbsp;V. P. Chornii,&nbsp;M. S. Slobodyanik\",\"doi\":\"10.1007/s11237-023-09769-2\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div><p>Solid solutions K<sub>2</sub>Bi(PO<sub>4</sub>)(MoO<sub>4</sub>):Gd,Eu containing from 0.1 to 30 mole% of europium(III) and 0.1 mole% of gadolinium(III) have been prepared by conventional solid state reaction. The samples are characterized by X-ray powder diffraction method, IR and luminescence spectroscopies. It has been shown that doping with Eu<sup>3+</sup> does not affect the symmetry of the layered framework. At room temperature, all the studied samples are characterized by intense red photoluminescence, which is associated with <sup>5</sup><i>D</i><sub>0</sub>→<sup>7</sup><i>F</i><sub>0-4</sub> emission transitions in Eu<sup>3+</sup> ions. Due to the absence of concentration quenching and color characteristics, K<sub>2</sub>Bi(PO<sub>4</sub>)(MoO<sub>4</sub>):Gd,Eu has prominent prospects for application as a red phosphor.</p></div></div>\",\"PeriodicalId\":796,\"journal\":{\"name\":\"Theoretical and Experimental Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.7000,\"publicationDate\":\"2023-07-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Theoretical and Experimental Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11237-023-09769-2\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Theoretical and Experimental Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s11237-023-09769-2","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

摘要

采用常规固相反应制备了含0.1 ~ 30摩尔%铕(III)和0.1摩尔%钆(III)的K2Bi(PO4)(MoO4):Gd,Eu固溶体。用x射线粉末衍射法、红外光谱和发光光谱对样品进行了表征。结果表明,掺入Eu3+并不影响层状骨架的对称性。在室温下,所有研究样品都表现出强烈的红色光致发光,这与Eu3+离子中的5D0→7F0-4发射跃迁有关。K2Bi(PO4)(MoO4):Gd,Eu作为红色荧光粉具有突出的应用前景。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

摘要图片

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
Luminescence Properties of K2Bi(PO4)(MoO4):Gd,Eu Solid Solutions

Solid solutions K2Bi(PO4)(MoO4):Gd,Eu containing from 0.1 to 30 mole% of europium(III) and 0.1 mole% of gadolinium(III) have been prepared by conventional solid state reaction. The samples are characterized by X-ray powder diffraction method, IR and luminescence spectroscopies. It has been shown that doping with Eu3+ does not affect the symmetry of the layered framework. At room temperature, all the studied samples are characterized by intense red photoluminescence, which is associated with 5D07F0-4 emission transitions in Eu3+ ions. Due to the absence of concentration quenching and color characteristics, K2Bi(PO4)(MoO4):Gd,Eu has prominent prospects for application as a red phosphor.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Theoretical and Experimental Chemistry
Theoretical and Experimental Chemistry CHEMISTRY, MULTIDISCIPLINARY-
CiteScore
1.60
自引率
10.00%
发文量
30
审稿时长
6-12 weeks
期刊介绍: Theoretical and Experimental Chemistry is a journal for the rapid publication of research communications and reviews on modern problems of physical chemistry such as: a) physicochemical bases, principles, and methods for creation of novel processes, compounds, and materials; b) physicochemical principles of chemical process control, influence of external physical forces on chemical reactions; c) physical nanochemistry, nanostructures and nanomaterials, functional nanomaterials, size-dependent properties of materials.
期刊最新文献
Initiation of Radical-Chain Aerobic Oxidation of Cumene by Potassium Permanganate and N-Hydroxysuccinimide Spin-Orbit Interaction During the Activation of Molecular Oxygen by Oxidases and Cofactor-Free Oxygenases: A Review Electrochemical Properties of Composites Based on Carbon Nanomaterials: A Review High-Temperature Spiro-(1,1′)-Bipyrrolidinium Tetrafluoroborate-Based Organic Electrolytes for Supercapacitors Vapor-Phase Carbonylation of Methanol with the Obtaining of Acetyls on Solid-Phase Catalysts: A Review
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1