M. A. Simonova, D. M. Ilgach, K. I. Kaskevich, M. I. Nepomnyashaya, L. S. Litvinova, A. P. Filippov, A. V. Yakimansky
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Self-assembly of Polyfluorene Molecular Brushes with Poly(methacrylic acid) Side Chains in Ethanol and Water
Graft copolymers with the polyfluorene backbone and poly(tert-butyl methacrylate) and poly(methacrylic acid) side chains are synthesized by atom transfer radical polymerization. The behavior of the synthesized brushes in chloroform, ethanol, and water solutions is studied by molecular hydrodynamics and optics. The graft copolymers are characterized by a high grafting density. The brushes with poly(methacrylic acid) side chains form unimolecular micelles capable of encapsulating curcumin in aqueous solutions. The grafting density of side chain affects the properties of brush complexes with curcumin.
期刊介绍：
Polymer Science, Series C (Selected Topics) is a journal published in collaboration with the Russian Academy of Sciences. Series C (Selected Topics) includes experimental and theoretical papers and reviews on the selected actual topics of macromolecular science chosen by the editorial board (1 issue a year). Submission is possible by invitation only. All journal series present original papers and reviews covering all fundamental aspects of macromolecular science. Contributions should be of marked novelty and interest for a broad readership. Articles may be written in English or Russian regardless of country and nationality of authors. All manuscripts are peer reviewed
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