Di TAN , Gui-ping TAN , Xiao-chun HUANG , Shan-ling TONG , Ke-er YANG , Yan YAN
{"title":"氮杂环与铜(II)和银(I)的顺式和反式配位组装","authors":"Di TAN , Gui-ping TAN , Xiao-chun HUANG , Shan-ling TONG , Ke-er YANG , Yan YAN","doi":"10.1016/S1005-9040(09)60001-5","DOIUrl":null,"url":null,"abstract":"<div><p>After the preparation of 1,4-bis(4,5-dihydro-1<em>H</em>-imidazol-2-yl)benzene(bdib), a nitrogen heterocycle with potential coordination manners of both <em>cis-</em> and <em>trans</em>-configuration forms, three complexes, including <em>cis</em>-[Cu<sub>2</sub>(bdib)<sub>2</sub>(μ-OCH<sub>3</sub>)<sub>2</sub>]Cl<sub>2</sub>·2MeOH(<strong>1</strong>), <em>trans</em>-[Cu(bdib)(AcO)<sub>2</sub>]<sub><em>n</em></sub>(<strong>2</strong>), and <em>cis</em>-[Ag<sub>2</sub>(bdib)<sub>2</sub>](NO<sub>3</sub>)<sub>2</sub>-2H<sub>2</sub>O(<strong>3</strong>), were successfully self-assembled. Complexes <strong>1</strong> and <strong>2</strong> crystallized in the monoclinic system with <em>P2<sub>1</sub>/n</em> space group and complex <strong>3</strong> in the triclinic system with <em>P</em>1 space group.</p></div>","PeriodicalId":9785,"journal":{"name":"Chemical Research in Chinese Universities","volume":"24 6","pages":"Pages 661-667"},"PeriodicalIF":3.1000,"publicationDate":"2008-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S1005-9040(09)60001-5","citationCount":"1","resultStr":"{\"title\":\"Cis- and Trans-Coordination Assembly of Nitrogen Heterocycle with Copper(II) and Silver(I)\",\"authors\":\"Di TAN , Gui-ping TAN , Xiao-chun HUANG , Shan-ling TONG , Ke-er YANG , Yan YAN\",\"doi\":\"10.1016/S1005-9040(09)60001-5\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>After the preparation of 1,4-bis(4,5-dihydro-1<em>H</em>-imidazol-2-yl)benzene(bdib), a nitrogen heterocycle with potential coordination manners of both <em>cis-</em> and <em>trans</em>-configuration forms, three complexes, including <em>cis</em>-[Cu<sub>2</sub>(bdib)<sub>2</sub>(μ-OCH<sub>3</sub>)<sub>2</sub>]Cl<sub>2</sub>·2MeOH(<strong>1</strong>), <em>trans</em>-[Cu(bdib)(AcO)<sub>2</sub>]<sub><em>n</em></sub>(<strong>2</strong>), and <em>cis</em>-[Ag<sub>2</sub>(bdib)<sub>2</sub>](NO<sub>3</sub>)<sub>2</sub>-2H<sub>2</sub>O(<strong>3</strong>), were successfully self-assembled. Complexes <strong>1</strong> and <strong>2</strong> crystallized in the monoclinic system with <em>P2<sub>1</sub>/n</em> space group and complex <strong>3</strong> in the triclinic system with <em>P</em>1 space group.</p></div>\",\"PeriodicalId\":9785,\"journal\":{\"name\":\"Chemical Research in Chinese Universities\",\"volume\":\"24 6\",\"pages\":\"Pages 661-667\"},\"PeriodicalIF\":3.1000,\"publicationDate\":\"2008-11-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/S1005-9040(09)60001-5\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Research in Chinese Universities\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1005904009600015\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Research in Chinese Universities","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1005904009600015","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Cis- and Trans-Coordination Assembly of Nitrogen Heterocycle with Copper(II) and Silver(I)
After the preparation of 1,4-bis(4,5-dihydro-1H-imidazol-2-yl)benzene(bdib), a nitrogen heterocycle with potential coordination manners of both cis- and trans-configuration forms, three complexes, including cis-[Cu2(bdib)2(μ-OCH3)2]Cl2·2MeOH(1), trans-[Cu(bdib)(AcO)2]n(2), and cis-[Ag2(bdib)2](NO3)2-2H2O(3), were successfully self-assembled. Complexes 1 and 2 crystallized in the monoclinic system with P21/n space group and complex 3 in the triclinic system with P1 space group.
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