氮杂环与铜(II)和银(I)的顺式和反式配位组装

IF 3.1 4区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Chemical Research in Chinese Universities Pub Date : 2008-11-01 DOI:10.1016/S1005-9040(09)60001-5
Di TAN , Gui-ping TAN , Xiao-chun HUANG , Shan-ling TONG , Ke-er YANG , Yan YAN
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引用次数: 1

摘要

在制备了具有顺式和反式两种配位方式的氮杂环1,4-双(4,5-二氢- 1h -咪唑-2-基)苯(bdib)后,成功地自组装了顺式-[Cu2(bdib)2(μ-OCH3)2]Cl2·2MeOH(1)、反式-[Cu(bdib)(AcO)2]n(2)和顺式-[Ag2(bdib)2](NO3)2- 2h2o(3)三个配合物。配合物1和2在具有P21/n空间群的单斜体系中结晶,配合物3在具有P1空间群的三斜体系中结晶。
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Cis- and Trans-Coordination Assembly of Nitrogen Heterocycle with Copper(II) and Silver(I)

After the preparation of 1,4-bis(4,5-dihydro-1H-imidazol-2-yl)benzene(bdib), a nitrogen heterocycle with potential coordination manners of both cis- and trans-configuration forms, three complexes, including cis-[Cu2(bdib)2(μ-OCH3)2]Cl2·2MeOH(1), trans-[Cu(bdib)(AcO)2]n(2), and cis-[Ag2(bdib)2](NO3)2-2H2O(3), were successfully self-assembled. Complexes 1 and 2 crystallized in the monoclinic system with P21/n space group and complex 3 in the triclinic system with P1 space group.

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来源期刊
CiteScore
5.30
自引率
6.50%
发文量
152
审稿时长
3.0 months
期刊介绍: The journal publishes research articles, letters/communications and reviews written by faculty members, researchers and postgraduates in universities, colleges and research institutes all over China and overseas. It reports the latest and most creative results of important fundamental research in all aspects of chemistry and of developments with significant consequences across subdisciplines. Main research areas include (but are not limited to): Organic chemistry (synthesis, characterization, and application); Inorganic chemistry (bio-inorganic chemistry, inorganic material chemistry); Analytical chemistry (especially chemometrics and the application of instrumental analysis and spectroscopy); Physical chemistry (mechanisms, catalysis, thermodynamics and dynamics); Polymer chemistry and polymer physics (mechanisms, material, catalysis, thermodynamics and dynamics); Quantum chemistry (quantum mechanical theory, quantum partition function, quantum statistical mechanics); Biochemistry; Biochemical engineering; Medicinal chemistry; Nanoscience (nanochemistry, nanomaterials).
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