{"title":"聚偏氯乙烯脱氢氯化动力学。第2部分。-紫外线预照射效果。γ射线和周围大气化学性质的影响","authors":"D. H. Everett, D. Taylor","doi":"10.1039/TF9716700402","DOIUrl":null,"url":null,"abstract":"This paper reports work on the influence on the kinetics of the first stage of decomposition of solid poly(vinylidene chloride) of pre-irradiation with u.-v. and γ-radiation, and of the chemical nature of the ambient atmosphere (vacuum, N2, air, O2, HCl, NO, ethylene, propylene, water vapour). The results lend support to the mechanism of the reaction proposed in part 1.","PeriodicalId":23290,"journal":{"name":"Transactions of The Faraday Society","volume":"67 1","pages":"402-413"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1039/TF9716700402","citationCount":"9","resultStr":"{\"title\":\"Kinetics of dehydrochlorination of poly(vinylidine chloride). Part 2.—Effect of pre-irradiation with U.-V. and γ-rays and the Influence of the chemical nature of the ambient atmosphere\",\"authors\":\"D. H. Everett, D. Taylor\",\"doi\":\"10.1039/TF9716700402\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"This paper reports work on the influence on the kinetics of the first stage of decomposition of solid poly(vinylidene chloride) of pre-irradiation with u.-v. and γ-radiation, and of the chemical nature of the ambient atmosphere (vacuum, N2, air, O2, HCl, NO, ethylene, propylene, water vapour). The results lend support to the mechanism of the reaction proposed in part 1.\",\"PeriodicalId\":23290,\"journal\":{\"name\":\"Transactions of The Faraday Society\",\"volume\":\"67 1\",\"pages\":\"402-413\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1039/TF9716700402\",\"citationCount\":\"9\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Transactions of The Faraday Society\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/TF9716700402\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Transactions of The Faraday Society","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/TF9716700402","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Kinetics of dehydrochlorination of poly(vinylidine chloride). Part 2.—Effect of pre-irradiation with U.-V. and γ-rays and the Influence of the chemical nature of the ambient atmosphere
This paper reports work on the influence on the kinetics of the first stage of decomposition of solid poly(vinylidene chloride) of pre-irradiation with u.-v. and γ-radiation, and of the chemical nature of the ambient atmosphere (vacuum, N2, air, O2, HCl, NO, ethylene, propylene, water vapour). The results lend support to the mechanism of the reaction proposed in part 1.