P. Dickens, A. Halliwell, D. J. Murphy, M. Whittingham
{"title":"六方铵钨青铜相(NH4)xWO3的制备与表征","authors":"P. Dickens, A. Halliwell, D. J. Murphy, M. Whittingham","doi":"10.1039/TF9716700794","DOIUrl":null,"url":null,"abstract":"The decomposition of ammonium paratungstate 5(NH4)2O.12WO3.5H2O in hydrogen has been studied thermogravimetrically and the formation of a hexagonal ammonium tungsten bronze phase, (NH4)xWO3(x∼0.25) established. Powder X-ray diffractometer studies, and measurements of electrical conductivity, magnetic susceptibility and reflectance spectra show that this phase is both iso-structural and iso-electronic with corresponding tungsten bronzes formed by potassium and rubidium.","PeriodicalId":23290,"journal":{"name":"Transactions of The Faraday Society","volume":"67 1","pages":"794-800"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1039/TF9716700794","citationCount":"38","resultStr":"{\"title\":\"Preparation and characterization of a hexagonal ammonium tungsten bronze phase (NH4)xWO3\",\"authors\":\"P. Dickens, A. Halliwell, D. J. Murphy, M. Whittingham\",\"doi\":\"10.1039/TF9716700794\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The decomposition of ammonium paratungstate 5(NH4)2O.12WO3.5H2O in hydrogen has been studied thermogravimetrically and the formation of a hexagonal ammonium tungsten bronze phase, (NH4)xWO3(x∼0.25) established. Powder X-ray diffractometer studies, and measurements of electrical conductivity, magnetic susceptibility and reflectance spectra show that this phase is both iso-structural and iso-electronic with corresponding tungsten bronzes formed by potassium and rubidium.\",\"PeriodicalId\":23290,\"journal\":{\"name\":\"Transactions of The Faraday Society\",\"volume\":\"67 1\",\"pages\":\"794-800\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1039/TF9716700794\",\"citationCount\":\"38\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Transactions of The Faraday Society\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/TF9716700794\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Transactions of The Faraday Society","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/TF9716700794","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Preparation and characterization of a hexagonal ammonium tungsten bronze phase (NH4)xWO3
The decomposition of ammonium paratungstate 5(NH4)2O.12WO3.5H2O in hydrogen has been studied thermogravimetrically and the formation of a hexagonal ammonium tungsten bronze phase, (NH4)xWO3(x∼0.25) established. Powder X-ray diffractometer studies, and measurements of electrical conductivity, magnetic susceptibility and reflectance spectra show that this phase is both iso-structural and iso-electronic with corresponding tungsten bronzes formed by potassium and rubidium.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
