“详细平衡在非平衡稳态中有对应项”的附录

Aditi Simha, R. Evans
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引用次数: 0

摘要

Evans(2004,2005)推导了连续驱动稳态(与剪切复杂流体相关)的过渡速率,要求除了使用系统的微观运动定律和宏观可观测值之外,不使用任何信息来描述它。这意味着系统与之弱耦合的(非平衡态)储层完全由其平均能量和平均通量表征。虽然我们期望在连续时间和离散时间模型中得到的速率处方是等效的,但从Evans(2005)中得出的速率表达式中看到这一点并非微不足道。我们证明了这个等效的激活过程的模型之前解决连续时间(Evans 2005),从而证明了理论的一致性。
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An Addendum to “Detailed Balance has a Counterpart in Nonequilibrium Steady States”
Transition rates in continuously driven steady states (relevant to sheared complex fluids) were derived in Evans (2004, 2005) by demanding that no information other than the microscopic laws of motion and the macroscopic observables of the system be used to describe it. This implies that the (nonequilibrium) reservoir, to which the system is weakly coupled, is fully characterized by its mean energy and mean flux. While we expect the resulting prescription for the rates in continuous- and discretized-time models to be equivalent, it is not trivial to see this from the expression for the rates derived in Evans (2005). We demonstrate this equivalence for a model of activated processes solved previously for continuous time (Evans 2005), thus demonstrating consistency of the theory.
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来源期刊
Transport Theory and Statistical Physics
Transport Theory and Statistical Physics 物理-物理:数学物理
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