W. Jackson, Leigh J. McJames, P. Newitt, Kerrina Wells
{"title":"八面体取代反应中的探查记忆效应:重排过程的新处理","authors":"W. Jackson, Leigh J. McJames, P. Newitt, Kerrina Wells","doi":"10.1080/1028662021000062554","DOIUrl":null,"url":null,"abstract":"The rates and steric course for the Me 2 SO substitution reactions for cis - and trans -[Co(en) 2 (OSMe 2 )(N 3 )] 2+ in solvent Me 2 SO have been investigated by 1 H NMR and Vis./UV spectroscopy. Isomerisation, racemisation, solvent exchange and NH scrambling experiments for selectively-deuterated complexes are reported which provide a wider picture on the octahedral substitution process and the nature of the intermediates than previously possible. The results show that the traditional accounts appearing in standard texts are in need of revamping.","PeriodicalId":54977,"journal":{"name":"Inorganic Reaction Mechanisms","volume":"26 1","pages":"141-157"},"PeriodicalIF":0.0000,"publicationDate":"2002-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Probing Memory Effects in Octahedral Substitution Reactions: New Handles on Rearrangement Processes\",\"authors\":\"W. Jackson, Leigh J. McJames, P. Newitt, Kerrina Wells\",\"doi\":\"10.1080/1028662021000062554\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The rates and steric course for the Me 2 SO substitution reactions for cis - and trans -[Co(en) 2 (OSMe 2 )(N 3 )] 2+ in solvent Me 2 SO have been investigated by 1 H NMR and Vis./UV spectroscopy. Isomerisation, racemisation, solvent exchange and NH scrambling experiments for selectively-deuterated complexes are reported which provide a wider picture on the octahedral substitution process and the nature of the intermediates than previously possible. The results show that the traditional accounts appearing in standard texts are in need of revamping.\",\"PeriodicalId\":54977,\"journal\":{\"name\":\"Inorganic Reaction Mechanisms\",\"volume\":\"26 1\",\"pages\":\"141-157\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2002-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Inorganic Reaction Mechanisms\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1080/1028662021000062554\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Inorganic Reaction Mechanisms","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/1028662021000062554","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Probing Memory Effects in Octahedral Substitution Reactions: New Handles on Rearrangement Processes
The rates and steric course for the Me 2 SO substitution reactions for cis - and trans -[Co(en) 2 (OSMe 2 )(N 3 )] 2+ in solvent Me 2 SO have been investigated by 1 H NMR and Vis./UV spectroscopy. Isomerisation, racemisation, solvent exchange and NH scrambling experiments for selectively-deuterated complexes are reported which provide a wider picture on the octahedral substitution process and the nature of the intermediates than previously possible. The results show that the traditional accounts appearing in standard texts are in need of revamping.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
