亲水石墨毡电化学检测重金属(Pb2+, Hg2+)性能评价

IF 2.3 Q3 ELECTROCHEMISTRY International journal of electrochemistry Pub Date : 2015-07-08 DOI:10.1155/2015/890425
Laila Bouabdalaoui, Benjamin Le Ouay, T. Coradin, C. Laberty‐Robert
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引用次数: 6

摘要

本文首次将亲水性石墨毡用于Hg2+的电化学检测,既可作为单一金属形态,又可与Pb2+同时检测。为此,建立了以海藻酸盐改性石墨毡为工作电极的方波伏安法(SWV)。石墨毡的结构,如高孔隙率和比表面积,加上良好的导电性,可以通过SWV方法获得较大的峰值电流,这表明海藻酸盐涂层有助于在碳表面预富集金属。所述电极成本低,易于操作,并且可以通过简单地将毛毡浸入金属溶液中进行电化学分析。
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Evaluation of Hydrophilized Graphite Felt for Electrochemical Heavy Metals Detection (Pb2+, Hg2+)
Hydrophilized graphite felt has been used, for the first time, for the electrochemical detection of Hg2+ ions both as single metal species and via its simultaneous detection with Pb2+. To do so, square wave voltammetry (SWV) method was developed with alginate modified graphite felt as working electrode. The structure of the graphite felt such as its high porosity and specific surface area coupled with its good electrical conductivity allows achieving large peak currents via the SWV method, suggesting that the alginate coating helps to preconcentrate metals at the carbon surface. The as-described electrode has low cost, it is easy to manipulate, and the electrochemical analysis can be performed by simple immersion of the felt in the metal solution.
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审稿时长
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