咖啡渣合成介孔活性炭及其吸附水溶液中锌和汞离子的研究

L. Giraldo, J. Moreno-Piraján
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引用次数: 58

摘要

以咖啡渣为前驱体,制备了具有高介孔率的活性炭,用于吸附大型吸附剂。由于其天然性质,咖啡渣具有较大的孔隙大小。本研究将咖啡渣用ZnCl2和KOH浸渍,然后分别在氮气条件下炭化和CO2活化。所得活性炭用于吸附离子Hg(II)和Zn(II)。这些吸附剂可以有效地从水溶液中去除这些离子,ACK3对Hg的单组分平衡吸附量为0.002 ~ 0.380 mmol∙g-1, ACZ3的单组分平衡吸附量为0.002 ~ 0.330 mmol∙g-1。ACK2上Zn(II)的变化范围为0.002 ~ 0.300 mmol∙g-1, ACZ2上Zn(II)的变化范围为0.001 ~ 0.274 mmol∙g-1。
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Synthesis of Activated Carbon Mesoporous from Coffee Waste and Its Application in Adsorption Zinc and Mercury Ions from Aqueous Solution
We obtain activated carbons with high portion of meso pores using coffee residues as precursor for the application of adsorption of large adsorbates. Because of its natural properties, the coffee residue exhibited a large pore size. In this work, the coffee residue were impregnated with ZnCl2 and KOH, and then carbonized under the nitrogen conditions and activated with CO2 respectively. Obtained activated carbons are used in the adsorption of ions Hg(II) and Zn(II). These adsorbents are efficacious to remove these ions from aqueous solution, with monocomponent equilibrium adsorption capacities ranging from from 0.002 to 0.380 mmol∙g-1 for Hg on ACK3 and from 0.002 to 0.330 mmol∙g-1 for ACZ3. For Zn(II) on ACK2 from 0.002 to 0.300 mmol∙g-1, and from 0.001 to 0.274 mmol∙g-1 for ACZ2.
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来源期刊
E-journal of Chemistry
E-journal of Chemistry CHEMISTRY, MULTIDISCIPLINARY-
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