二丁基锡(IV)-钛(IV)-μ-氧异丙醇水杨酸盐衍生物的合成与表征

R. Kumar
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引用次数: 0

摘要

通过μ-氧异丙醇化合物与不同水杨酸盐以不同的摩尔比(1:1-1:4)进行热缩合,合成了新型有机杂双金属-μ-氧异丙醇[Bu2SnO2Ti2(OPri)6] [Bu2SnO2Ti2(OPri)6-n(RSal)n](其中n = 1-4, RSal =水杨酸阴离子)化合物。μ-氧异丙醇衍生物通过元素、游离异丙醇和光谱分析(IR、1H、13C和119Sn NMR)进行了表征。
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Synthesis and Characterization of Salicylate Derivatives of Dibutyl Sn(IV)-Ti(IV)-μ-Oxoisopropoxide
New Salicylate derivatives of organoheterobimetallic-μ-oxoisopropoxide [Bu2SnO2Ti2(OPri)6] have been synthesized by the thermal condensation of μ-oxoisopropoxide compound with different salicylates in different molar ratios (1:1-1:4) yielded the compounds of the type [Bu2SnO2Ti2(OPri)6-n(RSal)n] (where n is 1-4 and RSal = Salicylate anion) respectively. The μ-oxoisopropoxide derivative has been characterized by elemental, liberated isopropanol, and spectral analysis (IR, 1H, 13C, and 119Sn NMR).
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E-journal of Chemistry
E-journal of Chemistry CHEMISTRY, MULTIDISCIPLINARY-
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