农业生物质与医用一次性口罩废弃物共热解绿色燃料研究进展及热动力学模型

IF 4.3 3区 工程技术 Q2 ENGINEERING, CHEMICAL Frontiers of Chemical Science and Engineering Pub Date : 2023-05-29 DOI:10.1007/s11705-022-2230-7
Melvin X. J. Wee, Bridgid L. F. Chin, Agus Saptoro, Chung L. Yiin, Jiuan J. Chew, Jaka Sunarso, Suzana Yusup, Abhishek Sharma
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引用次数: 1

摘要

东南亚国家联盟拥有得天独厚的农业资源,随着人口的不断增长,它将继续繁荣,这伴随着丰富的农业生物质。木质纤维素生物质吸引了研究人员从这些废物中提取生物油的兴趣。然而,由此产生的生物油具有低热值和不良的物理性能。因此,采用与塑料或聚合物废弃物共热解的方法来提高生物油的收率和质量。此外,随着新型冠状病毒的传播,一次性医用口罩等一次性塑料废物的激增可能会使之前的减少塑料废物措施受挫。因此,在探索一次性医用口罩废弃物作为生物质共热解候选物的潜力时,需要参考现有的技术和工艺。工艺参数、催化剂和技术的利用是改进和优化工艺以达到商业标准的关键因素。催化共热解涉及一系列复杂的机理,不能用简单的等转化模型来解释。因此,首先引入了先进的转换模型,然后是进化模型和预测模型,以解决非线性催化共热解反应动力学。详细讨论了本课题的前景和面临的挑战。
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A review on co-pyrolysis of agriculture biomass and disposable medical face mask waste for green fuel production: recent advances and thermo-kinetic models

The Association of Southeast Asian Nations is blessed with agricultural resources, and with the growing population, it will continue to prosper, which follows the abundance of agricultural biomass. Lignocellulosic biomass attracted researchers’ interest in extracting bio-oil from these wastes. However, the resulting bio-oil has low heating values and undesirable physical properties. Hence, co-pyrolysis with plastic or polymer wastes is adopted to improve the yield and quality of the bio-oil. Furthermore, with the spread of the novel coronavirus, the surge of single-use plastic waste such as disposable medical face mask, can potentially set back the previous plastic waste reduction measures. Therefore, studies of existing technologies and techniques are referred in exploring the potential of disposable medical face mask waste as a candidate for co-pyrolysis with biomass. Process parameters, utilisation of catalysts and technologies are key factors in improving and optimising the process to achieve commercial standard of liquid fuel. Catalytic co-pyrolysis involves a series of complex mechanisms, which cannot be explained using simple iso-conversional models. Hence, advanced conversional models are introduced, followed by the evolutionary models and predictive models, which can solve the non-linear catalytic co-pyrolysis reaction kinetics. The outlook and challenges for the topic are discussed in detail.

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来源期刊
CiteScore
7.60
自引率
6.70%
发文量
868
审稿时长
1 months
期刊介绍: Frontiers of Chemical Science and Engineering presents the latest developments in chemical science and engineering, emphasizing emerging and multidisciplinary fields and international trends in research and development. The journal promotes communication and exchange between scientists all over the world. The contents include original reviews, research papers and short communications. Coverage includes catalysis and reaction engineering, clean energy, functional material, nanotechnology and nanoscience, biomaterials and biotechnology, particle technology and multiphase processing, separation science and technology, sustainable technologies and green processing.
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