{"title":"硼酸和聚磷酸铵对松针热降解和可燃性的协同作用","authors":"L. Li, H. Hu, C. Guo","doi":"10.12841/WOOD.1644-3985.068.02","DOIUrl":null,"url":null,"abstract":"The synergistic effect of ammonium polyphosphate (APP) and boric acid (BA) on the flame retardancy and thermal degradation of pine needles was investigated. Thermogravimetric analysis (TGA) showed that the presence of an ammonium polyphosphate and boric acid system increased the char residue and decreased the pyrolysis temperature of the pine needles. The derivative thermogravimetric analysis (DTG) showed that the ammonium polyphosphate and boric acid had shifted the degradation peaks of the pine needles to lower temperatures. The cone calorimetry test results showed that the values of HRR, THR, SPR, TSP and the mass loss (%) of the pine needles treated with ammonium polyphosphate and boric acid (APP/BA = 3/2) were significantly lower than the other samples. Therefore, the APP and BA system had a better effect on the pine needles overall than the APP alone.","PeriodicalId":50566,"journal":{"name":"Drewno","volume":"57 1","pages":"37-49"},"PeriodicalIF":0.8000,"publicationDate":"2014-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"THE SYNERGISTIC EFFECT OF BORIC ACID AND AMMONIUM POLYPHOSPHATE ON THE THERMAL DEGRADATION AND FLAMMABILITY OF PINE-NEEDLES\",\"authors\":\"L. Li, H. Hu, C. Guo\",\"doi\":\"10.12841/WOOD.1644-3985.068.02\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The synergistic effect of ammonium polyphosphate (APP) and boric acid (BA) on the flame retardancy and thermal degradation of pine needles was investigated. Thermogravimetric analysis (TGA) showed that the presence of an ammonium polyphosphate and boric acid system increased the char residue and decreased the pyrolysis temperature of the pine needles. The derivative thermogravimetric analysis (DTG) showed that the ammonium polyphosphate and boric acid had shifted the degradation peaks of the pine needles to lower temperatures. The cone calorimetry test results showed that the values of HRR, THR, SPR, TSP and the mass loss (%) of the pine needles treated with ammonium polyphosphate and boric acid (APP/BA = 3/2) were significantly lower than the other samples. Therefore, the APP and BA system had a better effect on the pine needles overall than the APP alone.\",\"PeriodicalId\":50566,\"journal\":{\"name\":\"Drewno\",\"volume\":\"57 1\",\"pages\":\"37-49\"},\"PeriodicalIF\":0.8000,\"publicationDate\":\"2014-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Drewno\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.12841/WOOD.1644-3985.068.02\",\"RegionNum\":4,\"RegionCategory\":\"农林科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"MATERIALS SCIENCE, PAPER & WOOD\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Drewno","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.12841/WOOD.1644-3985.068.02","RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, PAPER & WOOD","Score":null,"Total":0}
THE SYNERGISTIC EFFECT OF BORIC ACID AND AMMONIUM POLYPHOSPHATE ON THE THERMAL DEGRADATION AND FLAMMABILITY OF PINE-NEEDLES
The synergistic effect of ammonium polyphosphate (APP) and boric acid (BA) on the flame retardancy and thermal degradation of pine needles was investigated. Thermogravimetric analysis (TGA) showed that the presence of an ammonium polyphosphate and boric acid system increased the char residue and decreased the pyrolysis temperature of the pine needles. The derivative thermogravimetric analysis (DTG) showed that the ammonium polyphosphate and boric acid had shifted the degradation peaks of the pine needles to lower temperatures. The cone calorimetry test results showed that the values of HRR, THR, SPR, TSP and the mass loss (%) of the pine needles treated with ammonium polyphosphate and boric acid (APP/BA = 3/2) were significantly lower than the other samples. Therefore, the APP and BA system had a better effect on the pine needles overall than the APP alone.
期刊介绍：
Wood. Research papers. Reports. Announcements" ("Drewno") is an international scientific journal that publishes original results of innovatory basic and applied research concerning technological, technical, economic and ecological issues important for the wood science and forest-based industries, including their environment, and interesting to the international recipients. "Drewno" is an Open Access biannual journal.
Aims and scope:
wood science: anatomy, biology, chemistry, physics
wood mechanical and chemical technology, inter alia, sawmilling, composite wood products, wooden construction, furniture making, wood pulp, paper making
material engineering, biocomposites, nanocomposites
material management
environmental protection, safety of the processes, products and working stations
biotechnology
bioenergy, biofuels
forestry: harvesting and wood quality
wood-based industries economics
The Editorial Board of the journal especially welcomes articles concerning increase in wood resources (wood mobilisation); innovative composites and lignocellulosic materials; new trends in the protection, modification and finishing of wood; biorefining of raw wood material; "green" building; new technologies of wood waste recycling; sustainable development; innovation management; and business networks.
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