掺杂水平对溶胶-凝胶法制备Sm3+掺杂BaWO4荧光粉发光效率的影响

H. He
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引用次数: 0

摘要

制备了Sm含量为0 ~ 7.5 at的Sm掺杂BaWO4荧光粉。%采用溶胶-凝胶法制备。利用x射线衍射分析、扫描电子显微镜和光致发光光谱分析表征了材料的微观结构和光致发光效率。研究了Sm掺杂水平的影响。随着钐掺杂水平的增加,纳米级平均粒径减小,颗粒形貌呈颗粒状。基质呈弱紫蓝色发射。BaWO4基体中的Sm3+呈现红色发射,明显强于基体的紫蓝色发射。Sm3+阳离子掺杂量最大时,Sm3+阳离子的发射效率最高。
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Doping level effect on the luminescence efficiency of Sm3+-doped BaWO4 phosphors prepared by sol-gel process
The Sm-doped BaWO4 phosphor powders with Sm content of 0-7.5 at.% were fabricated with a sol-gel method. X-ray diffraction analysis, scanning electron microscopy, and photoluminescence spectra analysis were used to characterise the microstructural and photoluminescence efficiency. The effect of Sm doping level was studied. A granular particle morphology and decreased nanoscale average particles size with increasing Sm-doping level were observed. The matrix showed weak violet-blue emission. The Sm3+ in the BaWO4 matrix showed red emission that is obviously stronger than violet-blue emission of the matrix. A maximal doping level of Sm3+ cation was observed for a highest emission efficiency of Sm3+ cation.
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