嗜血菌群对正聚磷酸盐对钢管防腐效果的影响——以“海探液”为例

E. Matelyuk, D. Charny, O. Kovalenko, Y. Onanko, S. Marysyk
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摘要

应当指出,在乌克兰运作的绝大多数供水系统是由易受腐蚀的钢或铸铁制成的。已经确定,降低饮用水腐蚀性的方法之一是使用正聚磷酸盐制剂“SeaQuest Liquid”(TU U 20.5-V 0502222-001:2017)。介绍了“SeaQuest Liquid”制剂对饮用水感官和理化指标影响的研究结果。结果表明,用“SeaQuest Liquid”制剂处理自来水不影响感官指标,在5个月的观察中,感官指标的平均水平几乎没有明显变化,在卫生标准范围内。在水样中,构成“SeaQuest Liquid”制剂的物质(多磷酸盐、正磷酸盐)的水平在正常值范围内。经“SeaQuest液”正磷酸盐制剂处理后的水质,除铁元素外,其他主要卫生化学指标均符合卫生标准DSanPiN 2.2.4.171-10的要求。部分水样铁含量超过卫生标准(0.2 mg/dm3),超过最大允许值(1.0 mg/dm3)。SeaQuest Liquid在次氯酸钠处理过的水中作用后,Langelier指数从-2,23下降到-2,08,从-1,79下降到-1,70,表明其腐蚀性下降。在未经次氯酸钠处理的水中,在“SeaQuest液体”制剂的影响下,观察到Langelier指数略有增加:从-1,80到-1,95,从-1,85到-2,78,从-2,01到-2,13,这表明其腐蚀性增加。在水中存在硫酸盐还原菌和硫杆菌的情况下,“SeaQuest Liquid”的制备使钢的腐蚀速率提高了2,9-7,2倍;用次氯酸钠对水进行额外消毒后,可将该指标降低1,4,2,7倍。
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INFLUENCE OF HEMOLITOTROPHIC MICROBIOTA ON THE EFFICIENCY OF ANTICORROSIVE TREATMENT OF STEEL PIPELINES WITH ORTHO-POLYPHOSPHATE REAGENTS ON THE EXAMPLE OF “SEA QUEST LIQUID”
It is noted that the overwhelming majority of water supply systems operating in Ukraine are made of steel or cast iron, which are subject to corrosion. It has been established that/ one of the ways to reduce the corrosiveness of drinking water is the use of an orthopolyphosphate preparation “SeaQuest Liquid” (TU U 20.5-V 0502222-001:2017). The results of studies of the effect of the “SeaQuest Liquid” preparation on organoleptic and physicochemical indicators of drinking water are presented. It was determined that the treatment of tap drinking water with the “SeaQuest Liquid” preparation does not affect organoleptic indicators, the average levels of which practically did not undergo significant changes during 5 months of observation and were within the hygienic standards. In water samples, the levels of substances that make up the “SeaQuest Liquid” preparation (polyphosphates, orthophosphates) were within the normative values. The quality of water treated with the “SeaQuest Liquid” orthophosphate preparation, according to the main sanitary and chemical indicators, except for iron, meets the requirements of the hygienic standards DSanPiN 2.2.4.171-10. In some water samples, the iron content in water exceeded the hygienic standard (0.2 mg/dm3) and went beyond the maximum permissible level (1.0 mg/dm3). Under the action of “SeaQuest Liquid” in water treated with sodium hypochlorite, a decrease in the Langelier index was observed: from -2,23 to -2,08 and from -1,79 to -1,70, which indicates a decrease in its corrosivity. In water untreated with sodium hypochlorite under the influence of the “SeaQuest Liquid” preparation, a slight increase in the Langelier index was observed: from -1,80 to -1,95 and from -1,85 to -2,78, from -2,01 to -2,13, which indicates an increase in its corrosiveness. In the presence of sulphate-reducing and thiobacteria in water, the “SeaQuest Liquid” preparation increases the corrosion rate of steel by 2,9-7,2 times; subject to additional disinfection of water with sodium hypochlorite, it reduces this indicator by 1,4-2,7 times.
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