利用ZnCl2激活,从咖啡渣中提取活性碳的过程

Rasdiansyah Rasdiansyah, Darmadi Darmadi, M. D. Supardan
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引用次数: 2

摘要

活性炭可以由多种含有碳元素的原料制成。咖啡渣是一种丰富而有发展前景的活性炭原料。以ZnCl2为活化剂,对咖啡渣生产活性炭的优化工艺进行了研究。采用响应面法,采用Box-Behnken设计对影响活性炭质量的因素进行优化。所使用的因素是碳化温度(T),分别为400℃、500℃和600℃;ZnCl2 (K)浓度分别为30%、40%、50%;氯化锌与活性炭的质量比分别为2:1、3:1和4:1。活性炭吸附碘的二阶回归模型为Y = 626、2 - 36、5T + 28、6K - 36、5R + 31、2T2 + 47、1K2 - 0、5R2 - 19、0TK + 15、9TR + 101、5KR。优化工艺结果表明,碳化温度为400℃,ZnCl2浓度为30%,ZnCl2与活性炭质量比为2:1时,吸附碘量为799.659 mg/g。
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Optimasi Proses Pembuatan Karbon Aktif dari Ampas Bubuk Kopi Menggunakan Aktivator ZnCl2
Activated carbon can be manufactured from a variety source materials containing element carbon. Dregs of coffee grounds is one of abundant and promising activated carbon raw materials. This study was conducted to assess optimization process of activated carbon production from dregs of coffee grounds by using ZnCl2 as an activator. The optimization process is performed by using Response Surface Method to optimize factors that affected quality of the activated carbon using Box-Behnken design. The factors used were carbonation temperature (T) with a level of 400 oC, 500 oC and 600 °C; concentration of ZnCl2 (K) with a level of 30%, 40%, 50%; and mass ratio of ZnCl2 to activated carbon with level of 2:1, 3:1 and 4:1. A second order regression model of iodine absorption of activated carbon was Y = 626,2 - 36,5T + 28,6K - 36,5R + 31,2T2 + 47,1K2 - 0,5R2 - 19,0TK + 15,9TR + 101,5KR. Results of optimization process showed that optimum iodine absorption of 799.659 mg/g was obtained at the following conditions, i.e. carbonation temperature of 400 oC, ZnCl2 concentration of 30% and mass ratio of ZnCl2 to activated carbon of 2:1.
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