{"title":"皮下和相互输入接到键中的安宁合成元素具体的高利族和印第安酒精细胞","authors":"M. Veith, J. Pöhlmann","doi":"10.22028/D291-24008","DOIUrl":null,"url":null,"abstract":"The lithium alkoxoamidosilane (Me2Si(OtBu)(NtBu)2 (4) and its trimethyltin derivative Me2Si(OtBu)(NtBu)SnMe3 (7) have been used, to introduce the ligand Me2Si(Otbu)(NtBu) = L into molecular compounds of gallium and indium. The following molecules were synthesized : L-M(Me)Cl (M = Ga(5), In (6)), L-InMe2 (8); L-InX2 (X = Cl (9), Br(10)), L2InX (X = Cl of temperature dependent 1H NmR spectra. the chelating effect is more pronounced in the gallium derivatives than in the indium analogues. Equilibria between L2InX/InX3 and LInx2 have bee observed in diethylether solutions. No metal(I) deribatibes LGa or LIn could be isolated. L2Ga2Cl2 (22), formally containing gallium(II), can be sublimed without decomposition at 110°C in vacuo.","PeriodicalId":51215,"journal":{"name":"Zeitschrift Fur Naturforschung Section B-A Journal of Chemical Sciences","volume":"43 1","pages":"505-512"},"PeriodicalIF":0.8000,"publicationDate":"1988-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Stickstoffverbindungen von Elementen der dritten Hauptgruppe mit intra- und intermolekularen Donor-Akzeptor-Bindungen. - V : Spezielle Gallium- und Indium-amide mit Alkoxogruppen\",\"authors\":\"M. Veith, J. Pöhlmann\",\"doi\":\"10.22028/D291-24008\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The lithium alkoxoamidosilane (Me2Si(OtBu)(NtBu)2 (4) and its trimethyltin derivative Me2Si(OtBu)(NtBu)SnMe3 (7) have been used, to introduce the ligand Me2Si(Otbu)(NtBu) = L into molecular compounds of gallium and indium. The following molecules were synthesized : L-M(Me)Cl (M = Ga(5), In (6)), L-InMe2 (8); L-InX2 (X = Cl (9), Br(10)), L2InX (X = Cl of temperature dependent 1H NmR spectra. the chelating effect is more pronounced in the gallium derivatives than in the indium analogues. Equilibria between L2InX/InX3 and LInx2 have bee observed in diethylether solutions. No metal(I) deribatibes LGa or LIn could be isolated. L2Ga2Cl2 (22), formally containing gallium(II), can be sublimed without decomposition at 110°C in vacuo.\",\"PeriodicalId\":51215,\"journal\":{\"name\":\"Zeitschrift Fur Naturforschung Section B-A Journal of Chemical Sciences\",\"volume\":\"43 1\",\"pages\":\"505-512\"},\"PeriodicalIF\":0.8000,\"publicationDate\":\"1988-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Zeitschrift Fur Naturforschung Section B-A Journal of Chemical Sciences\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.22028/D291-24008\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Zeitschrift Fur Naturforschung Section B-A Journal of Chemical Sciences","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.22028/D291-24008","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Stickstoffverbindungen von Elementen der dritten Hauptgruppe mit intra- und intermolekularen Donor-Akzeptor-Bindungen. - V : Spezielle Gallium- und Indium-amide mit Alkoxogruppen
The lithium alkoxoamidosilane (Me2Si(OtBu)(NtBu)2 (4) and its trimethyltin derivative Me2Si(OtBu)(NtBu)SnMe3 (7) have been used, to introduce the ligand Me2Si(Otbu)(NtBu) = L into molecular compounds of gallium and indium. The following molecules were synthesized : L-M(Me)Cl (M = Ga(5), In (6)), L-InMe2 (8); L-InX2 (X = Cl (9), Br(10)), L2InX (X = Cl of temperature dependent 1H NmR spectra. the chelating effect is more pronounced in the gallium derivatives than in the indium analogues. Equilibria between L2InX/InX3 and LInx2 have bee observed in diethylether solutions. No metal(I) deribatibes LGa or LIn could be isolated. L2Ga2Cl2 (22), formally containing gallium(II), can be sublimed without decomposition at 110°C in vacuo.
期刊介绍：
Zeitschrift fuer Naturforschung B (ZNB) publishes novel research in all areas of inorganic chemistry, organic chemistry, and analytical chemistry. In particular, the journal focuses on solid state chemistry, coordination chemistry, main group element chemistry, synthetic organic chemistry, natural product chemistry and, to a lesser extent, on analytical chemistry. For more than 65 years Zeitschrift fuer Naturforschung B has been open to contributions from all fields of experimental and theoretical chemistry. Zeitschrift fuer Naturforschung B publishes 12 issues per volume/year. Sometimes double issues occur.
Topics
Solid state chemistry
Coordination chemistry
Main group element chemistry
Organic chemistry
Natural product chemistry.
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