溶致层状相取向转变动力学

Q4 Engineering Journal of Biorheology Pub Date : 2016-01-01 DOI:10.17106/JBR.30.27
S. Fujii, Yuki Yamamoto
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引用次数: 2

摘要

用粘度法研究了三嵌段共聚物片层相的取向转变动力学。我们发现应变控制机制主导了转变动力学。我们从位错动力学的角度提出了一种取向转变的可能情况。我们还可以通过假设位错在剪切作用下的极限速度来计算取向转变的临界剪切速率。计算值与实验观测值吻合较好。位错的成核可能是取向转变的必要条件。
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Kinetics of the orientation transition in the lyotropic lamellar phase
Kinetics of the orientation transition in the triblock copolymer lamellar phase is studied by viscometry. We find that the strain-controlled mechanism dominates the transition kinetics. We propose a possible scenario of the orientation transition from the viewpoint of the dislocation dynamics. We could also evaluate the critical shear rate of the orientation transition by assuming the limiting velocity of the dislocations under shear. evaluated value is in good agreement with the experimental observation. the nucleation of the dislocations might be necessary for the orientation transition.
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来源期刊
Journal of Biorheology
Journal of Biorheology Engineering-Mechanical Engineering
CiteScore
0.50
自引率
0.00%
发文量
5
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