利用有机质和粘土含量评价农业土壤中微量元素MPC

R. Pivić, Z. Dinić, J. Maksimović, D. Poštić, R. Štrbanović, A. Stanojković-Sebić
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引用次数: 2

摘要

本文的目的是研究有机质和粘土含量对微量元素Pb、Ni、Cr和Cd的最大允许浓度(MPC)值的影响。维利科格拉迪斯特市境内的天然土壤。分析了82个营养性cambisol型土壤样品,17个黑钙土样品,32个沙土样品。在0 ~ 30 cm深度的复合土壤样品中,土壤肥力的主要参数(pH、P2O5、K2O、CaCO3、土壤有机质- SOM)、粘裂缝含量?测定了铅、镍、铬和镉的总形态。根据法规(官方公报,88/2018)中定义的微量元素MPC对所获得的结果进行了解释。根据定义的MPC值与校正值的比值(校正值的计算包括有机质和粘土含量的值),确定了被测样品中有机质含量与粘土组分含量的相关性。此外,被试土壤中Cr和Pb的含量仍未超过调整后的MPC值。Cd和Ni与MPC的建立值和修正值均无偏差。最后,研究应继续进行并补充其他类型土壤的数据,这将为进一步评估来自荷兰的现有法规的适用性奠定基础,并将其纳入塞尔维亚法规(Official Gazette, 88/2018)。
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Evaluation of trace elements MPC in agricultural soil using organic matter and clay content
The aim of this paper is to investigate the contribution of the influence of organic matter and clay content on the value of maximum permissible concentrations (MPC) of trace elements Pb, Ni, Cr, and Cd. The investigation was conducted on agricul?tural soil in the territory of Veliko Gradiste Municipality. There were analyzed 82 samples of eutric cambisol type soil, 17 samples of chernozem soil, and 32 samples of sandy soil. In the composite soil samples, taken from a depth of 0-30 cm, main parameters of soil fertility (pH, P2O5, K2O, CaCO3, soil organic matter - SOM), the content of the clay frac?tion, and total forms of Pb, Ni, Cr, and Cd were determined. Interpretation of the obtained results was carried out in relation to the MPC of trace elements defined in the Regulations (Official Gazette, 88/2018). Based on the ratio of the defined MPC and corrected values whose calculation includes the values of the organic matter and clay content, there was determined the correlation concerning the content of organic matter and the content of clay fractions, respectively, in the tested samples. In addition, the content of Cr and Pb in tested types of soil still did not exceed the adjusted MPC value. As for Cd and Ni, there was no deviation from the established and modified values of MPC. Concludingly, the research should be continued and supplemented by data for other types of soils, which would represent a base for a further assessment of the applicability of the existing regulations taken from Dutch sources and incorporated into Serbian Regulations (Official Gazette, 88/2018).
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