{"title":"在蒙脱土钠层上组装过渡金属氧化物用于阴离子聚合丙烯酸甲酯丁酯","authors":"Ameen Abdelrahman, A. Radwan, A. Zaki, A. Hamouda","doi":"10.22052/JNS.2021.01.001","DOIUrl":null,"url":null,"abstract":"In the present study, Anionic polymerization of Butyl Methyl acrylate has been carried out in oxygen atmosphere over different heterogenic prepared catalytic systems which is composed of a group of three metal oxides ( Ti, Mn Cu ) assembled on thin layers of clay ( Bentonite ) as hydrogenating/dehydrogenating activation for the polymerization reaction. The prepared catalysts and polymeric products were distinguished by different spectroscopic techniques such as XRD , 1HNMR, ,energy-dispersive X-ray spectroscopy (EDX), SCN TEM, IR, and gel permeation chromatography(GPC). we deduced that the dimensions of the efficiency of each catalyst as well as whole composites on the polymerization of Butyl Methyl acrylate of process, also, we approach the reaction mechanism of the polymeric process, furthermore, studying the variation and factors affecting on anionic polymerization like polydispersity index and tactility properties, we approached more details and discussion were deeply investigated in blow throughout figures and applicable data analysis.","PeriodicalId":16523,"journal":{"name":"Journal of Nanostructures","volume":"11 1","pages":"1-12"},"PeriodicalIF":1.4000,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Assembling a Bunch of Transition Metals Oxides on Sodium Montmorillonite Layer for Anionic Polymerization of Butyl Methyl Acrylate\",\"authors\":\"Ameen Abdelrahman, A. Radwan, A. Zaki, A. Hamouda\",\"doi\":\"10.22052/JNS.2021.01.001\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"In the present study, Anionic polymerization of Butyl Methyl acrylate has been carried out in oxygen atmosphere over different heterogenic prepared catalytic systems which is composed of a group of three metal oxides ( Ti, Mn Cu ) assembled on thin layers of clay ( Bentonite ) as hydrogenating/dehydrogenating activation for the polymerization reaction. The prepared catalysts and polymeric products were distinguished by different spectroscopic techniques such as XRD , 1HNMR, ,energy-dispersive X-ray spectroscopy (EDX), SCN TEM, IR, and gel permeation chromatography(GPC). we deduced that the dimensions of the efficiency of each catalyst as well as whole composites on the polymerization of Butyl Methyl acrylate of process, also, we approach the reaction mechanism of the polymeric process, furthermore, studying the variation and factors affecting on anionic polymerization like polydispersity index and tactility properties, we approached more details and discussion were deeply investigated in blow throughout figures and applicable data analysis.\",\"PeriodicalId\":16523,\"journal\":{\"name\":\"Journal of Nanostructures\",\"volume\":\"11 1\",\"pages\":\"1-12\"},\"PeriodicalIF\":1.4000,\"publicationDate\":\"2021-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Nanostructures\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.22052/JNS.2021.01.001\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"NANOSCIENCE & NANOTECHNOLOGY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Nanostructures","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.22052/JNS.2021.01.001","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"NANOSCIENCE & NANOTECHNOLOGY","Score":null,"Total":0}
Assembling a Bunch of Transition Metals Oxides on Sodium Montmorillonite Layer for Anionic Polymerization of Butyl Methyl Acrylate
In the present study, Anionic polymerization of Butyl Methyl acrylate has been carried out in oxygen atmosphere over different heterogenic prepared catalytic systems which is composed of a group of three metal oxides ( Ti, Mn Cu ) assembled on thin layers of clay ( Bentonite ) as hydrogenating/dehydrogenating activation for the polymerization reaction. The prepared catalysts and polymeric products were distinguished by different spectroscopic techniques such as XRD , 1HNMR, ,energy-dispersive X-ray spectroscopy (EDX), SCN TEM, IR, and gel permeation chromatography(GPC). we deduced that the dimensions of the efficiency of each catalyst as well as whole composites on the polymerization of Butyl Methyl acrylate of process, also, we approach the reaction mechanism of the polymeric process, furthermore, studying the variation and factors affecting on anionic polymerization like polydispersity index and tactility properties, we approached more details and discussion were deeply investigated in blow throughout figures and applicable data analysis.
期刊介绍:
Journal of Nanostructures is a medium for global academics to exchange and disseminate their knowledge as well as the latest discoveries and advances in the science and engineering of nanostructured materials. Topics covered in the journal include, but are not limited to the following: Nanosystems for solar cell, energy, catalytic and environmental applications Quantum dots, nanocrystalline materials, nanoparticles, nanocomposites Characterization of nanostructures and size dependent properties Fullerenes, carbon nanotubes and graphene Self-assembly and molecular organization Super hydrophobic surface and material Synthesis of nanostructured materials Nanobiotechnology and nanomedicine Functionalization of nanostructures Nanomagnetics Nanosensors.