以哈萨克斯坦天然原料为原料制备改性吸附剂及其性能研究

IF 0.8 Q4 METALLURGY & METALLURGICAL ENGINEERING Kompleksnoe Ispolzovanie Mineralnogo Syra Pub Date : 2022-05-02 DOI:10.31643/2022/6445.25
Surkova T.Yu, Baltabekova Zh.A, Surkova Tatiana, Yuryevna, B. Beisembayev, Abdikerim Bekzat Erubayuly, Berkinbayeva Ainur Nurkaliyevna
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引用次数: 1

摘要

哈萨克斯坦已探明的钾盐储量巨大,但钾肥仍然没有生产,而钾肥的需求却在不断增长。因此,研究将最大的切尔卡矿床矿石加工成钾肥和盐类是一个迫切需要解决的问题。介绍了硝酸分解和硝酸悬浮液过滤洗钾矿的研究结果。研究了不溶性废渣的过滤性能和颗粒组成,在此基础上确定了沉淀物双重洗涤的分解方式。为保证良好的悬浮滤过性,应使用水洗的、未煅烧的矿石。对副产品石膏作为石膏粘结剂进行了试验,证实了其与g - 2b级正常硬化石膏粘结剂的一致性。所得石膏的优点是环境友好。用硝酸溶液结晶法制备了无氯水溶性钾镁肥盐。根据试验和室内试验的结果,制定了从Chelkar矿床矿石中获得钾肥和复合钾氮镁肥的基本流程方案。
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Obtaining modified sorbents based on natural raw materials of Kazakhstan and research of their properties
With the huge explored reserves of potash salts in Kazakhstan, there is still no production of potash fertilizers, the demand for which is constantly growing. In this regard, research of processing of the largest Chelkar deposit ore into potash fertilizers and salts is an urgent problem. The article presents the research results of washed potash ore decomposition with nitric acid and nitric acid suspension filtration. The filtering properties and granulometric composition of the insoluble residue were studied, on what basis the decomposition mode with precipitate double washing was determined. To ensure good suspension filterability, washed, uncalcined ore should be used. Tests of a by-product, gypsum, as a gypsum binder were carried out, which confirmed its compliance with the normally hardening gypsum binder of the G-2 B grade. Advantage of the obtained gypsum is its environmental friendliness. Salts, which are chlorine-free water-soluble potassium-magnesium fertilizers have been obtained by crystallization from nitric acid solution. On the basis of results of experimental-and-laboratory tests, a basic flow scheme has been developed for obtaining potash and complex potassium-nitrogen-magnesium fertilizers from the Chelkar deposit ore.
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