环氧树脂作为金属防腐涂料的研究进展

IF 0.8 Q4 METALLURGY & METALLURGICAL ENGINEERING Kompleksnoe Ispolzovanie Mineralnogo Syra Pub Date : 2023-07-05 DOI:10.31643/2024/6445.03
A. Makhmetova, E. Negim, D. Ainakulova, G. Yeligbayeva, J. Khatib
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引用次数: 0

摘要

任何用于建筑工作的金属结构,都必须从质量上保护其不受外部环境的影响,更确切地说,是防止腐蚀的发展。在环境的影响下,由于腐蚀过程,金属失去了它的性能。腐蚀的存在降低了生产中任何设备的使用寿命,使产品质量恶化。为解决设备、建筑、结构等金属的使用寿命延长和化学防护问题,需要采用高效的环氧树脂防腐涂料。这些材料具有耐化学性,并提供屏障,限制腐蚀性介质进入涂层表面。环氧树脂对卤素、酸和碱的作用稳定,对金属有很高的附着力。然而,由于聚合物大分子空间网络节点间的迁移性有限,环氧树脂具有复杂的积极性质,但也有明显的缺点——高可燃性、刚度和相对较低的物理和机械性能,包括抗冲击性。因此,环氧树脂用各种硬化剂固化,并与各种填料(金属、矿物和有机)和许多其他组分混合,以降低材料成本,并使树脂本身的性能朝着期望的方向得到改善。本文综述了环氧树脂的基本性能,各种硬化剂和改性剂对环氧涂料防腐性能的影响,以及环氧树脂的一般应用和使用对健康的危害。
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An Overview of Epoxy Resins as coating to protect metals from corrosion
Any structures of metal, which are used in construction work, must be qualitatively protected from the external environment, more precisely, from the development of corrosion. Under the influence of the environment as a result of corrosive processes, the metal loses its properties. The presence of corrosion reduces the service life of any equipment in production, it worsens the quality of products. To solve the problems of increasing service life and providing chemical protection of metal, which is made of equipment, constructions, and structures, use highly effective anti-corrosion coatings based on epoxy resins. These materials are chemically resistant and provide a barrier that limits the access of corrosive media to the coated surface. Epoxy resins are stable to the action of halogens, acids, and alkalis, and have high adhesion to metals. However, having a complex of positive properties, epoxy resins have significant disadvantages - high combustibility, stiffness, and relatively low physical and mechanical properties, including resistance to impact, due to the limited mobility of inter-nodal sites of the spatial network of polymer macromolecules. Therefore, epoxy is cured with various hardeners and mixed with a variety of fillers (metallic, mineral, and organic), and many other components to reduce the cost of materials and to allow the properties of the resins themselves to be improved in the desired direction. This overview article discusses the basic properties of epoxy resins and the effects of various hardeners, and modifiers on the anti-corrosive properties of epoxy coatings, as well as general applications of epoxy resins and the health risks of their use.
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