{"title":"用“结构决定性质”原理比较亲核性和碱性","authors":"Xingyu Chen, Xinyu Li, Zhiqian Wang","doi":"10.3866/pku.dxhx201912070","DOIUrl":null,"url":null,"abstract":": This paper provides a practical explanation of the comparison between nucleophilicity and basicity of nucleophiles. The similarities are explained based on the principle of “structure determines property”, and the differences are explained by combining Hard-Soft-Acid-Base theory and the steric hindrance factor.","PeriodicalId":23447,"journal":{"name":"University Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2020-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Comparison between Nucleophilicity and Basicity Using the Principle of “Structure Determines Properties”\",\"authors\":\"Xingyu Chen, Xinyu Li, Zhiqian Wang\",\"doi\":\"10.3866/pku.dxhx201912070\",\"DOIUrl\":null,\"url\":null,\"abstract\":\": This paper provides a practical explanation of the comparison between nucleophilicity and basicity of nucleophiles. The similarities are explained based on the principle of “structure determines property”, and the differences are explained by combining Hard-Soft-Acid-Base theory and the steric hindrance factor.\",\"PeriodicalId\":23447,\"journal\":{\"name\":\"University Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2020-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"University Chemistry\",\"FirstCategoryId\":\"95\",\"ListUrlMain\":\"https://doi.org/10.3866/pku.dxhx201912070\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"University Chemistry","FirstCategoryId":"95","ListUrlMain":"https://doi.org/10.3866/pku.dxhx201912070","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Comparison between Nucleophilicity and Basicity Using the Principle of “Structure Determines Properties”
: This paper provides a practical explanation of the comparison between nucleophilicity and basicity of nucleophiles. The similarities are explained based on the principle of “structure determines property”, and the differences are explained by combining Hard-Soft-Acid-Base theory and the steric hindrance factor.
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