{"title":"低分子量混合溶液对聚合物P4MP1膜的选择性分子吸收","authors":"A. Chiba, R. Akiyama","doi":"10.4131/jshpreview.31.82","DOIUrl":null,"url":null,"abstract":"Recently isotactic poly(4methyl1pentene) (P4MP1) has been found to selectively absorb long-chain alkanes from alkane mixed systems. In this article, we introduce the idea of this study from the pressure-temperature phase diagram. We also show that such selective absorption characteristics can be explained from a simple model, namely Asakura-Oosawa theory, and the relationship with molecular recognition is explained. [host-guest structures, selective absorption, Asakura-Oosawa theory, molecular recognition, melting curve maximum, P4MP1, PMP, SPS]","PeriodicalId":39932,"journal":{"name":"Review of High Pressure Science and Technology/Koatsuryoku No Kagaku To Gijutsu","volume":"1 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Selective Molecular Absorption from Low Molecular Weight Mixed Solution to a Polymer P4MP1 Film\",\"authors\":\"A. Chiba, R. Akiyama\",\"doi\":\"10.4131/jshpreview.31.82\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Recently isotactic poly(4methyl1pentene) (P4MP1) has been found to selectively absorb long-chain alkanes from alkane mixed systems. In this article, we introduce the idea of this study from the pressure-temperature phase diagram. We also show that such selective absorption characteristics can be explained from a simple model, namely Asakura-Oosawa theory, and the relationship with molecular recognition is explained. [host-guest structures, selective absorption, Asakura-Oosawa theory, molecular recognition, melting curve maximum, P4MP1, PMP, SPS]\",\"PeriodicalId\":39932,\"journal\":{\"name\":\"Review of High Pressure Science and Technology/Koatsuryoku No Kagaku To Gijutsu\",\"volume\":\"1 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2021-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Review of High Pressure Science and Technology/Koatsuryoku No Kagaku To Gijutsu\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.4131/jshpreview.31.82\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Review of High Pressure Science and Technology/Koatsuryoku No Kagaku To Gijutsu","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.4131/jshpreview.31.82","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Selective Molecular Absorption from Low Molecular Weight Mixed Solution to a Polymer P4MP1 Film
Recently isotactic poly(4methyl1pentene) (P4MP1) has been found to selectively absorb long-chain alkanes from alkane mixed systems. In this article, we introduce the idea of this study from the pressure-temperature phase diagram. We also show that such selective absorption characteristics can be explained from a simple model, namely Asakura-Oosawa theory, and the relationship with molecular recognition is explained. [host-guest structures, selective absorption, Asakura-Oosawa theory, molecular recognition, melting curve maximum, P4MP1, PMP, SPS]
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