Chemical Fingerprints and Source Profiles of PM10 and PM2.5 from Agricultural Soil in a Typical Polluted Region of Northwest China

Analysis of the chemical source profiles of agricultural soil dust (SD) can help accurately assess and apportion the contribution of agricultural sources to atmospheric particulate matter (PM). This study quantitatively analysed twenty-four elements, eight water-soluble ions, organic carbon (OC) and elemental carbon (EC) in PM 10 and PM 2.5 samples from agricultural resuspended SD to understand the chemical profiles of agricultural SD in Baoji city, Northwest China. The results showed that the elemental compositions in the PM 10 and PM 2.5 size fractions contributed 40.18% and 39.6%, respectively, followed by water-soluble ions (3.85% in PM 10 and 6.62% in PM 2.5 ) and carbonaceous fractions (3.46% in PM 10 and 2.36% in PM 2.5 ). The reconstructed crustal matter estimated from Al, Si, Ca, Ti, and Fe concentrations accounted for 79.58% and 78.8% of the total PM 10 and PM 2.5 , respectively, indicating that crustal matter may be the most significant contributor to agricultural SD PM 10 and PM 2.5 mass. Agricultural SD was influenced not only by the long-range transport of Asian dust but also by local anthropogenic sources. Higher Sc, As, Ca 2+ , NO 3– , and NH 4+ in PM 2.5 indicated that agricultural SD was strongly influenced by anthropogenic industrial and agricultural activities. The ratios of Si/Al, Ca/Al, K/Al, Fe/Al, and Ti/Fe in Baoji samples are basically consistent with those of Asian dust, indicating that the long-range transport of Asian dust had an important impact on the elemental composition of agricultural SD. Source identification found that higher NH 4+ /Al, NO 3– /Ca 2+ , NO 3– /SO 42– ratios, and OC can be considered possible source indicators.