关于生物圈热平衡和辐射波长变化引起的熵变的一些看法

J. Velasco
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引用次数: 0

摘要

对生物圈的热平衡进行了解释,这种平衡是基于从太阳接收的热能与从大气反射到空间的热能相等。为了理解引起生物圈中发生的过程和现象的能量的来源,有必要考虑由温度乘以熵变T△S的乘积所表示的自由能,其大小可归因于波长(或因此,构成从太阳接收到的辐射光谱的辐射的频率与从生物圈重新发射到太空的辐射光谱的频率的比较。通过简单的讨论可以预测,驱动这些过程的熵增加与高频辐射(熵的“含量”较低)在低频辐射(熵的“含量”较高)中的自发转换有关。这样做的结果是,高频辐射对应于更有序的状态,因此,与低频辐射对应的状态相比,高频辐射对应于更不可能的状态。
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Some Ideas about the Thermal Equilibrium in the Biosphere and the Entropy Variation Ascribed to Changes in the Radiations Wavelengths
An explanation is given for the thermal equilibrium in the biosphere, which is based in the equality between the thermal energy received from the sun and the thermal energy reemitted from the atmosphere to the space. In order to understand the origin of the energy that gives rise to the processes and phenomena taking place in the biosphere, it is necessary to take into account the free energy represented by the product of temperature times the change in entropy, T△S, whose magnitude can be attributed to the variation experimented by the wavelengths (or, consequently, the frequencies) of the radiations composing the radiation spectrum received from the sun compared with the radiation spectrum reemitted from the biosphere into the space. A simple discussion allows to predict that the entropy increase driving the processes is connected with a spontaneous conversion of high frequency radiations (with lower “content” of entropy) in radiations of lower frequencies (with higher “content” of entropy). A consequence of this is that high frequency radiations would correspond to more ordered states and, therefore, to less probable states than those corresponding to radiations of lower frequencies.
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