持久性有机农药二嗪农的光降解研究进展

IF 0.6 4区 化学 Q4 CHEMISTRY, MULTIDISCIPLINARY Journal of the chemical society of pakistan Pub Date : 2022-01-01 DOI:10.52568/001120/jcsp/44.05.2022
Fawad Ahmad Fawad Ahmad, Sana Nisar Sana Nisar, Maira Mehmood Maira Mehmood, Zakiratullah Zakiratullah
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引用次数: 0

摘要

农药在世界范围内的广泛生产、利用和报废,由于其生物持久性和生物蓄积性,增加了人类和动物的健康问题。在现有的处理方法中,基于金属氧化物的光催化技术是一种新兴的水介质农药去除技术,由于其可行性、成本效益和较高的降解率,近年来引起了许多研究者的兴趣。本文综述了金属氧化物光催化降解的机理、农药降解的反应动力学、优化操作参数以提高降解过程,并分析了二元、三元或金属/非金属掺杂金属氧化物光催化剂以提高降解效果的不同修饰。综述了催化剂投加量、pH、初始农药浓度、紫外/日照、照射时间等操作参数对农药光催化降解的影响。综述了各种光催化剂在水介质中降解二嗪醌的性能。然而,需要进一步的研究来实现快速和最大程度的降解,以保持环境安全。
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A Critical Review on the Photo Degradation of Diazinon, A Persistent Organic Pesticides
Broad production, utilization, and scrapping of pesticides worldwide increase the health concern of humans and animals, due to their bio-persistent and bio-accumulating nature. Among the present treatment methods, metaloxide based photocatalysis is the emerging technology for pesticide removal in aqueous medium, and has gained the interest of many researchers in the past years due to its feasibility, cost efficiency and higher degradation rate. This review briefly discusses the mechanism of metaloxide based photocatalytic degradation, reaction kinetics of pesticides degradation, optimization of operational parameters to enhance the degradation process, and different modifications such as binary, ternary or metal/non-metal dopped metaloxide photocatalysts to improve the effectiveness of degradation has also been analyzed. The effect of operational parameters like effect of catalyst dosage, pH, initial pesticide concentration, UV/sunlight, and irradiation time on the photocatalytic degradation of pesticide has been reviewed. The comparison of various photocatalysts for the degradation of diazinon from aqueous medium is summarized. However additional research is required to achieve fast and maximum degradation to keep the environment safe.
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来源期刊
CiteScore
1.30
自引率
14.30%
发文量
41
审稿时长
3.4 months
期刊介绍: This journal covers different research areas in the field of Chemistry. These include; Analytical Chemistry, Applied Chemistry, Biochemistry, Environmental Chemistry, Industrial Chemistry, Inorganic Chemistry, Organic Chemistry and Physical Chemistry. The journal publishes full length articles and Reviews from researchers in academia in addition to featuring comments. Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry.
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