铂(II)的酰胺配合物作为硝酸根离子的受体

Chantelle R. Bondy , Philip A. Gale , Stephen J. Loeb
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引用次数: 30

摘要

两个3,5-二丁基酰胺吡啶配体与[Pt(4,4′-tBu-2,2′-bopy)]2+片段(具有非配位PF6-阴离子)的顺式配位产生了具有四个能够与客体阴离子氢键的酰胺基的正方形平面络合物。1H NMR光谱用于评估含氧阴离子NO3−、ReO4−、CF3SO3−、H2PO4−、HSO4−、CH3COO−和C6H5COO−与受体的结合。NO3−加合物的X射线晶体结构显示了受体-底物相互作用的细节,并解释了为什么该受体与先前报道的Pt(II)的四(烟酰胺)复合物相比没有改善,后者对硝酸根和乙酸根离子具有选择性。
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Amido complexes of platinum(II) as receptors for the nitrate ion
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