研磨“固体-气体”系统机械化学演化的直接分析

A. Nonat, J.C. Mutin
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引用次数: 1

摘要

开发了一种用于直接分析固体-气体系统机械化学演化的原始装置。在恒定的气体压力和温度下测量机械反应过程中释放或封闭的气体体积。对几种羟基化合物和水合物进行了研磨实验。他们表明,这种方法非常方便系统地研究通过研磨或机械处理和随后的热解进行的固体-气体反应的热力学和动力学特性。
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Analyse directe de l'evolution mecanochimique de systemes “solide-gaz” soumis au broyage

An original device for direct analysis of the mechanochemical evolution of solid-gas systems has been developed.

The volume of gas evolved or occluded during the mechanical reaction is measured under constant gaseous pressure and temperature.

Grinding experiments have been performed on several hydroxydes and hydrates. They show that this method is very convenient for the systematic study of the thermodynamic and kinetic characteristics of solid-gas reactions carried out either by grinding or by mechanical treatment and subsequent thermolysis.

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Materials Chemistry Materials Chemistry Author index On the separation of the contributions of powder particle cores and intergranular contacts to the electric resistivity of the compressed powder materials Vingt ans apres: To Karplus or not to Karplus?
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