{"title":"研磨“固体-气体”系统机械化学演化的直接分析","authors":"A. Nonat, J.C. Mutin","doi":"10.1016/0390-6035(82)90089-X","DOIUrl":null,"url":null,"abstract":"<div><p>An original device for direct analysis of the mechanochemical evolution of solid-gas systems has been developed.</p><p>The volume of gas evolved or occluded during the mechanical reaction is measured under constant gaseous pressure and temperature.</p><p>Grinding experiments have been performed on several hydroxydes and hydrates. They show that this method is very convenient for the systematic study of the thermodynamic and kinetic characteristics of solid-gas reactions carried out either by grinding or by mechanical treatment and subsequent thermolysis.</p></div>","PeriodicalId":18221,"journal":{"name":"Materials Chemistry","volume":"7 4","pages":"Pages 455-478"},"PeriodicalIF":0.0000,"publicationDate":"1982-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0390-6035(82)90089-X","citationCount":"1","resultStr":"{\"title\":\"Analyse directe de l'evolution mecanochimique de systemes “solide-gaz” soumis au broyage\",\"authors\":\"A. Nonat, J.C. Mutin\",\"doi\":\"10.1016/0390-6035(82)90089-X\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>An original device for direct analysis of the mechanochemical evolution of solid-gas systems has been developed.</p><p>The volume of gas evolved or occluded during the mechanical reaction is measured under constant gaseous pressure and temperature.</p><p>Grinding experiments have been performed on several hydroxydes and hydrates. They show that this method is very convenient for the systematic study of the thermodynamic and kinetic characteristics of solid-gas reactions carried out either by grinding or by mechanical treatment and subsequent thermolysis.</p></div>\",\"PeriodicalId\":18221,\"journal\":{\"name\":\"Materials Chemistry\",\"volume\":\"7 4\",\"pages\":\"Pages 455-478\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1982-07-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0390-6035(82)90089-X\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Materials Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/039060358290089X\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/039060358290089X","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Analyse directe de l'evolution mecanochimique de systemes “solide-gaz” soumis au broyage
An original device for direct analysis of the mechanochemical evolution of solid-gas systems has been developed.
The volume of gas evolved or occluded during the mechanical reaction is measured under constant gaseous pressure and temperature.
Grinding experiments have been performed on several hydroxydes and hydrates. They show that this method is very convenient for the systematic study of the thermodynamic and kinetic characteristics of solid-gas reactions carried out either by grinding or by mechanical treatment and subsequent thermolysis.