Ni(II)–Zn(II)杂双核配合物的晶体结构和化学性质

Gianluca Ambrosi , Paolo Dapporto , Mauro Formica , Vieri Fusi , Luca Giorgi , Annalisa Guerri , Mauro Micheloni , Paola Paoli , Patrizia Rossi
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引用次数: 5

摘要

通过混合Ni(II)和Zn(II)的双核配合物,制备了2-双-(氨基乙基)-氨基甲基苯酚(L)的双核Ni(Ⅱ)–Zn(Ⅱ)配合物。用X射线分析对混合杂双核配合物进行了表征。化合物[NiZn(H-1L)2(H2O)2][ClO4]2的晶体数据表明它是单斜的;空间群P21/n,其中a=20.137(2)Å,b=9.480(1)Å、c=15.934(1)å、β=100.45(1)°、V=2991.3(5)Å3、Z=4、R=0.094。
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Crystal Structure and Chemical Properties of Ni(II)–Zn(II) Hetero-Dinuclear Complex
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