氨基三叔丁基酞菁的合成及其对二氧化氮的气敏性

W.P. Hu, Y.Q. Liu, S.G. Liu, S.Q. Zhou, D.B. Zhu
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引用次数: 5

摘要

氨基三叔丁基酞菁(AmBuPc)是一种新型不对称酞菁,具有3个叔丁基和1个氨基。所有取代基都是给电子基,当它们与氧化性气体(如NO2)相互作用时具有很强的给电子能力。本文报道了该化合物的合成及其对二氧化氮的气敏性,并揭示了该化合物的电化学性质。
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The synthesis of aminotri-tert-butyl phthalocyanine and its gas sensitivity to nitrogen dioxide

Aminotri-tert-butyl phthalocyanine (AmBuPc) is a new asymmetrical phthalocyanine, which possesses three tert-butyl groups and one amino-group. All the substituents are electron-donating ones and have a strong electron-donating ability when they interact with oxidizing gases, such as NO2. We report its synthesis and its gas sensitivity to nitrogen dioxide, and reveal the electrochemical properties of this compound.

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