{"title":"三种具有柔性双三唑和刚性苯二甲酸盐配体的锰配位聚合物的合成、结构和发光","authors":"Jian‐Xin Chen, Xia Zhu, Shan Zhao, Bao‐Long Li, Zhang Yong","doi":"10.1080/15533174.2015.1137044","DOIUrl":null,"url":null,"abstract":"Three Mn(II) coordination polymers, {[Mn(bte)0.5(bdc)(H2O)]•H2O} (1), {[Mn(bte)(I-bdc)(H2O)]•H2O}n (2), and [Mn(btp)(bdc)(H2O)]•2.5H2O (3), were synthesized (bte = 1,2-bis(1,2,4-triazol-1-yl)ethane, btp = 1,3-bis(1,2,4-triazol-1-yl)propane, bdc = 1,3-benzenebiscarboxylate, I-bdc = 5-iodoisophthalate). 1 is an unusual (3,4)-connected 2D network with the point symbol of (42•6)(42•63•8). 2 is an independent 1D metal-organic nanotube (MONT). The combination of rings and two chains forms independent 1D MONT. The I groups of each 1D MONT polythread into two adjacent 1D MONTs to form a (1D → 2D) polythreaded array. 3 shows the undulated 2D (4,4) network and a double-layer hydrogen bonding network. The luminescence and thermal stability were investigated.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2016-04-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":"{\"title\":\"Syntheses, Structures, and Luminescence of Three Manganese Coordination Polymers With Flexible Bistriazole and Rigid Benzenedicarboxylate Ligands\",\"authors\":\"Jian‐Xin Chen, Xia Zhu, Shan Zhao, Bao‐Long Li, Zhang Yong\",\"doi\":\"10.1080/15533174.2015.1137044\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Three Mn(II) coordination polymers, {[Mn(bte)0.5(bdc)(H2O)]•H2O} (1), {[Mn(bte)(I-bdc)(H2O)]•H2O}n (2), and [Mn(btp)(bdc)(H2O)]•2.5H2O (3), were synthesized (bte = 1,2-bis(1,2,4-triazol-1-yl)ethane, btp = 1,3-bis(1,2,4-triazol-1-yl)propane, bdc = 1,3-benzenebiscarboxylate, I-bdc = 5-iodoisophthalate). 1 is an unusual (3,4)-connected 2D network with the point symbol of (42•6)(42•63•8). 2 is an independent 1D metal-organic nanotube (MONT). The combination of rings and two chains forms independent 1D MONT. The I groups of each 1D MONT polythread into two adjacent 1D MONTs to form a (1D → 2D) polythreaded array. 3 shows the undulated 2D (4,4) network and a double-layer hydrogen bonding network. The luminescence and thermal stability were investigated.\",\"PeriodicalId\":22118,\"journal\":{\"name\":\"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2016-04-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"2\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1080/15533174.2015.1137044\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/15533174.2015.1137044","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Syntheses, Structures, and Luminescence of Three Manganese Coordination Polymers With Flexible Bistriazole and Rigid Benzenedicarboxylate Ligands
Three Mn(II) coordination polymers, {[Mn(bte)0.5(bdc)(H2O)]•H2O} (1), {[Mn(bte)(I-bdc)(H2O)]•H2O}n (2), and [Mn(btp)(bdc)(H2O)]•2.5H2O (3), were synthesized (bte = 1,2-bis(1,2,4-triazol-1-yl)ethane, btp = 1,3-bis(1,2,4-triazol-1-yl)propane, bdc = 1,3-benzenebiscarboxylate, I-bdc = 5-iodoisophthalate). 1 is an unusual (3,4)-connected 2D network with the point symbol of (42•6)(42•63•8). 2 is an independent 1D metal-organic nanotube (MONT). The combination of rings and two chains forms independent 1D MONT. The I groups of each 1D MONT polythread into two adjacent 1D MONTs to form a (1D → 2D) polythreaded array. 3 shows the undulated 2D (4,4) network and a double-layer hydrogen bonding network. The luminescence and thermal stability were investigated.
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