贮存条件对褐煤品质影响的研究

Vasile Bobei, D. Ciolea
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摘要

煤层中空气相对湿度的微小增加会导致煤层含水率增加1%,从而导致自燃的可能性。通过将新开采的煤沉积在已经在矿床中的煤上,在物理和化学性质方面具有不同特征的两个表面之间存在直接接触,从而使后者起到底漆的作用。温度较高的煤把多余的温度让给温度较低的煤,从而引发自热核的形成,然后是自燃核。这种现象在季节较冷的时期很容易观察到,特别是通常在雨后,当两种煤之间的温度交换产生的蒸汽被释放到大气中。常见的原因是水蒸气通过沉积物的运动与煤颗粒的吸附有关。蒸汽在贮存温度下的冷凝热约为580卡/克水。将煤的重量从3%增加到4%所需的水量压缩,会使煤的温度升高170摄氏度以上。温度的升高足以使氧化速率提高5倍。
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Studies on Lignite Quality Depending on Storage Conditions
Abstract A small increase in the relative humidity in the air in a coal deposit can cause a 1% increase in the moisture content of the deposit resulting in the probability of spontaneous ignition. By depositing the freshly extracted coal over the coal already in the deposit, there is a direct contact between the two surfaces that have different characteristics in terms of physical and chemical properties, so that the latter acts as a primer. The coal with a higher temperature gives up the excess temperature to the coal with a lower temperature, thus initiating the formation of self-heating nuclei followed by self-ignition ones. The phenomenon is easy to observe in the colder periods of the season and especially usually after rain, when the vapors resulting from the exchange of temperature between the two types of coal are released into the atmosphere. The common cause is the movement of water vapor through the deposit correlated with the adsorption on the coal granules. The heat of condensation of vapor at storage temperature is about 580 cal./gram of water. Condensing the amount of water required to increase the content from 3% of the weight of the coal to 4% leads to an increase in the temperature of the coal by more than 170C. This increase in temperature is sufficient to increase the oxidation rate by 5 times.
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