V. Serheyev, S. Gerasymchuk, H. Melnyk, B. Y. Vоdко
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APPLICATION OF WILSON'S MODEL FOR DESCRIPTION OF PHASE EQUILIBRIUM OF VAPOR LIQUID FOR AZEOTROPIC SYSTEM ACETIC ACID – ACRYLIC ACID
Based on data on the composition of azeotropic solutions for the acetic acid - acrylic acid system, the parameters of the semi-empirical Wilson model for temperatures 320, 330, 340, 350 K were calculated using the mathematical software package Mathcad 14 by iterations. The obtained parameters made it possible to describe the vapor-liquid equilibrium in the acetic acid-acrylic acid system: to calculate the composition of the equilibrium phases, the activity coefficients of the solution components, the separation coefficient and to construct p-x isothermal boil diagrams.
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