A. Ciocarlan, L. Lungu, S. Blaja, I. Dragalin, A. Aricu
{"title":"几种非常规化学方法在双环二聚甲醛甲酯合成中的应用","authors":"A. Ciocarlan, L. Lungu, S. Blaja, I. Dragalin, A. Aricu","doi":"10.19261/cjm.2020.791","DOIUrl":null,"url":null,"abstract":"The present paper reports the results of microwave irradiation assisted method for the preparation of bicyclohomofarnesenic methyl esters versus classical Stoll and Hinder method. Moreover, the chemical transformations of bicyclohomofarnesenic methyl esters via anodic electrooxidation and dye-sensitized photooxidation were performed. A new method for the preparation of methyl 7-oxo-13,14,15,16-tetranorlabd-6,8(8)-dien-12-oate and the mechanism of electrochemical products formation are presented. The structure of all synthesized compounds was fully confirmed by spectral methods.","PeriodicalId":9922,"journal":{"name":"Chemistry Journal of Moldova","volume":"5 1","pages":""},"PeriodicalIF":0.5000,"publicationDate":"2020-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"3","resultStr":"{\"title\":\"The Use of Some Non-conventional Methods in Chemistry of Bicyclohomofarnesenic Methyl Esters\",\"authors\":\"A. Ciocarlan, L. Lungu, S. Blaja, I. Dragalin, A. Aricu\",\"doi\":\"10.19261/cjm.2020.791\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The present paper reports the results of microwave irradiation assisted method for the preparation of bicyclohomofarnesenic methyl esters versus classical Stoll and Hinder method. Moreover, the chemical transformations of bicyclohomofarnesenic methyl esters via anodic electrooxidation and dye-sensitized photooxidation were performed. A new method for the preparation of methyl 7-oxo-13,14,15,16-tetranorlabd-6,8(8)-dien-12-oate and the mechanism of electrochemical products formation are presented. The structure of all synthesized compounds was fully confirmed by spectral methods.\",\"PeriodicalId\":9922,\"journal\":{\"name\":\"Chemistry Journal of Moldova\",\"volume\":\"5 1\",\"pages\":\"\"},\"PeriodicalIF\":0.5000,\"publicationDate\":\"2020-12-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"3\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemistry Journal of Moldova\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.19261/cjm.2020.791\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemistry Journal of Moldova","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.19261/cjm.2020.791","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
The Use of Some Non-conventional Methods in Chemistry of Bicyclohomofarnesenic Methyl Esters
The present paper reports the results of microwave irradiation assisted method for the preparation of bicyclohomofarnesenic methyl esters versus classical Stoll and Hinder method. Moreover, the chemical transformations of bicyclohomofarnesenic methyl esters via anodic electrooxidation and dye-sensitized photooxidation were performed. A new method for the preparation of methyl 7-oxo-13,14,15,16-tetranorlabd-6,8(8)-dien-12-oate and the mechanism of electrochemical products formation are presented. The structure of all synthesized compounds was fully confirmed by spectral methods.
期刊介绍:
"Chemistry Journal of Moldova. General, Industrial and Ecological Chemistry" seeks to publish experimental or theoretical research results of outstanding significance and timeliness in all fields of Chemistry, including Industrial and Ecological Chemistry. The main goal of this edition is strengthening the Chemical Society of Moldova, following development of research in Moldovan chemical institutions and promotion of their collaboration with international chemical community. Manuscripts are welcome from all countries.