金属羰基化学。十五。二羰基双-(三苯基膦)铑阴离子[Rh(CO)2(PPh3)2] -与一些全氟芳香化合物的反应

B. Booth, R. Haszeldine, Ian Perkins
{"title":"金属羰基化学。十五。二羰基双-(三苯基膦)铑阴离子[Rh(CO)2(PPh3)2] -与一些全氟芳香化合物的反应","authors":"B. Booth, R. Haszeldine, Ian Perkins","doi":"10.1039/J19710000927","DOIUrl":null,"url":null,"abstract":"The carbonylmetal anion [Rh(CO)2(PPh3)2]– has been shown to be a strong nucleophile of similar power to that of [(π-C5H5)Fe(CO)2]– or [(π-C5H5)Ru(CO)2]–. Its reactions with the compounds C6F6, C6F5X (X = CN or CO2Et), (NC)2C6F4, C5F5N, and 2-(NC)C5F4N to afford some new perfluoroaromatic rhodium(l) complexes are discussed.","PeriodicalId":17321,"journal":{"name":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"6","resultStr":"{\"title\":\"Metal carbonyl chemistry. Part XV. Reactions of the dicarbonylbis-(triphenylphosphine)rhodate anion, [Rh(CO)2(PPh3)2]–, with some perfluoroaromatic compounds\",\"authors\":\"B. Booth, R. Haszeldine, Ian Perkins\",\"doi\":\"10.1039/J19710000927\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The carbonylmetal anion [Rh(CO)2(PPh3)2]– has been shown to be a strong nucleophile of similar power to that of [(π-C5H5)Fe(CO)2]– or [(π-C5H5)Ru(CO)2]–. Its reactions with the compounds C6F6, C6F5X (X = CN or CO2Et), (NC)2C6F4, C5F5N, and 2-(NC)C5F4N to afford some new perfluoroaromatic rhodium(l) complexes are discussed.\",\"PeriodicalId\":17321,\"journal\":{\"name\":\"Journal of The Chemical Society A: Inorganic, Physical, Theoretical\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"6\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society A: Inorganic, Physical, Theoretical\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/J19710000927\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/J19710000927","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 6

摘要

羰基金属阴离子[Rh(CO)2(PPh3)2] -是与[(π-C5H5)Fe(CO)2] -或[(π-C5H5)Ru(CO)2] -相似的强亲核试剂。讨论了它与化合物C6F6、C6F5X (X = CN或CO2Et)、(NC)2C6F4、C5F5N和2-(NC)C5F4N反应生成一些新的全氟芳香铑(l)配合物。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
Metal carbonyl chemistry. Part XV. Reactions of the dicarbonylbis-(triphenylphosphine)rhodate anion, [Rh(CO)2(PPh3)2]–, with some perfluoroaromatic compounds
The carbonylmetal anion [Rh(CO)2(PPh3)2]– has been shown to be a strong nucleophile of similar power to that of [(π-C5H5)Fe(CO)2]– or [(π-C5H5)Ru(CO)2]–. Its reactions with the compounds C6F6, C6F5X (X = CN or CO2Et), (NC)2C6F4, C5F5N, and 2-(NC)C5F4N to afford some new perfluoroaromatic rhodium(l) complexes are discussed.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
自引率
0.00%
发文量
0
期刊最新文献
The interpretation of carbon nuclear magnetic resonance shifts Trimethyl-silyl, -germyl and -stannyl complexes of platinum Positive-ion mass spectra of some polychloro-organomercurials Single-crystal electronic and electron spin resonance spectra of bis(ethoxyacetato)bisaquocopper(II) Structures of some hexacarbonyl-(π-dienyl)iron–cobalt complexes, [(π-ring)Fe(CO)2Co(CO)4], and the ruthenium compound [(π-C5H5)Ru(CO)2Co(CO)4]
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1