金属羰基化学。十五。二羰基双-(三苯基膦)铑阴离子[Rh(CO)2(PPh3)2] -与一些全氟芳香化合物的反应

Journal of The Chemical Society A: Inorganic, Physical, Theoretical Pub Date : 1971-01-01 DOI:10.1039/J19710000927

B. Booth, R. Haszeldine, Ian Perkins

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引用次数: 6

摘要

羰基金属阴离子[Rh(CO)2(PPh3)2] -是与[(π-C5H5)Fe(CO)2] -或[(π-C5H5)Ru(CO)2] -相似的强亲核试剂。讨论了它与化合物C6F6、C6F5X (X = CN或CO2Et)、(NC)2C6F4、C5F5N和2-(NC)C5F4N反应生成一些新的全氟芳香铑(l)配合物。

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Metal carbonyl chemistry. Part XV. Reactions of the dicarbonylbis-(triphenylphosphine)rhodate anion, [Rh(CO)2(PPh3)2]–, with some perfluoroaromatic compounds

The carbonylmetal anion [Rh(CO)2(PPh3)2]– has been shown to be a strong nucleophile of similar power to that of [(π-C5H5)Fe(CO)2]– or [(π-C5H5)Ru(CO)2]–. Its reactions with the compounds C6F6, C6F5X (X = CN or CO2Et), (NC)2C6F4, C5F5N, and 2-(NC)C5F4N to afford some new perfluoroaromatic rhodium(l) complexes are discussed.

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Journal of The Chemical Society A: Inorganic, Physical, Theoretical

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