三价元素对MCM-41介孔分子材料热、水热稳定性的影响

Nongyue He , Zuhong Lu , Chunwei Yuan , Jianming Hong , Chun Yang , Shulin Bao , Qinhua Xu
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引用次数: 12

摘要

研究了三价元素对MCM-41介孔分子筛材料热稳定性和水热稳定性的影响。Al(III)降低了MCM-41材料的热稳定性和水热稳定性,而La(III)和Fe(III),尤其是Fe(III)提高了材料的热稳定性和水热稳定性。对苯的吸附和红外光谱分析表明,较厚的通道壁和较少的结构缺陷位点可以提高MCM-41的热稳定性和水热稳定性。
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Effect of trivalent elements on the thermal and hydrothermal stability of MCM-41 mesoporous molecular materials

Effect of trivalent elements on the thermal and hydrothermal stability of MCM-41 mesoporous molecular sieve materials has been investigated. Al(III) decreases the thermal and hydrothermal stability of MCM-41 materials, whereas La(III) and Fe(III), especially Fe(III), can improve the thermal and hydrothermal stability. Benzene adsorption and IR spectra suggested that thick channel wall and the fewer structural defect sites in MCM-41 would enhance the thermal and hydrothermal stability of MCM-41.

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