木粉颗粒燃烧动力学的实验研究

IF 1.5 Q3 ENGINEERING, CHEMICAL Journal of Combustion Pub Date : 2018-09-02 DOI:10.1155/2018/5981598
Peng Haobin, Yuesheng Li, Yunquan Li, Fangyang Yuan, Guohua Chen
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引用次数: 8

摘要

采用热重分析仪(TGA)和管式炉系统对木粉和木颗粒的燃烧动力学特性进行了研究。分别用双步双等温法和等温法测定和推导了两种不同形式木质燃料的动力学参数。结果表明:木粉的燃烧机理在整个燃烧过程中保持一致,而木屑颗粒的燃烧机理在挥发分和炭燃烧阶段存在显著差异。两种不同形式的木质燃料的最可能的机理功能是不相同的,这是由于内部传热和传质性质的差异。木粉的活化能为92.33 kJ·mol−1 ~ 71.20 kJ·mol−1,木粉的指前因子值(2.55×108 s−1)远大于木颗粒的指前因子值(78.55 s−1),相差7个数量级。
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Experimental Investigation of Combustion Kinetics of Wood Powder and Pellet
The combustion kinetic characteristics of wood powder and pellet were investigated within thermogravimetric analyser (TGA) and tube furnace system. The kinetic parameters of these two different forms of woody fuel were measured and derived by double-step-and-double-equal and isothermal method, respectively. The results showed that the combustion mechanisms of wood powder kept consistent through the whole process, while the combustion mechanisms of wood pellet differed significantly between the volatile and char combustion stages. The most probable mechanism functions of the two different forms of woody fuel were not the same due to the differences in internal heat and mass transfer properties. In addition, activation energy values varied from 92.33 kJ·mol−1 for wood powder to 71.20 kJ·mol−1 for wood pellet, while the preexponential factor value of wood powder (2.55×108 s−1) was far greater than the one of the wood pellet (78.55 s−1) by seven orders of magnitude.
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来源期刊
Journal of Combustion
Journal of Combustion ENGINEERING, CHEMICAL-
CiteScore
2.00
自引率
28.60%
发文量
8
审稿时长
20 weeks
期刊最新文献
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