{"title":"电子冲击发光光谱和中性碎片。利用碎片发射鉴定中性碎片","authors":"Akinori Inoue, Shuji Yoshida, Nozomu Ebara","doi":"10.1016/0020-7381(83)85042-6","DOIUrl":null,"url":null,"abstract":"<div><p>Electron-impact luminescence spectra were measured for cyclohexanol, acetic acid, pyridine, pyrimidine, benzonitrile, aniline, nitrobenzene, <em>p</em>-methoxy-nitrobenzene, 1-chlorobutane, 1-chloropentane, tetrahydrofuran and anisole. The spectra were analyzed and compared with the literature data of mass spectrometry. It was found that fragment emissions of OH(A<sup>2</sup>Σ<sup>+</sup>-X<sup>2</sup>Π), CN(B<sup>2</sup>Σ-X<sup>2</sup>Σ), NO(B<sup>2</sup>Π-X<sup>2</sup>Π) and HCl<sup>+</sup>(A<sup>2</sup>Σ-X<sup>2</sup>Π) can be used for the identification of neutral fragments of OH and H<sub>2</sub>O, HCN, NO and HCl, respectively.</p></div>","PeriodicalId":13998,"journal":{"name":"International Journal of Mass Spectrometry and Ion Physics","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1983-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0020-7381(83)85042-6","citationCount":"4","resultStr":"{\"title\":\"Electron-impact luminescence spectra and neutral fragments: Identification of neutral fragments by use of fragment emissions\",\"authors\":\"Akinori Inoue, Shuji Yoshida, Nozomu Ebara\",\"doi\":\"10.1016/0020-7381(83)85042-6\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Electron-impact luminescence spectra were measured for cyclohexanol, acetic acid, pyridine, pyrimidine, benzonitrile, aniline, nitrobenzene, <em>p</em>-methoxy-nitrobenzene, 1-chlorobutane, 1-chloropentane, tetrahydrofuran and anisole. The spectra were analyzed and compared with the literature data of mass spectrometry. It was found that fragment emissions of OH(A<sup>2</sup>Σ<sup>+</sup>-X<sup>2</sup>Π), CN(B<sup>2</sup>Σ-X<sup>2</sup>Σ), NO(B<sup>2</sup>Π-X<sup>2</sup>Π) and HCl<sup>+</sup>(A<sup>2</sup>Σ-X<sup>2</sup>Π) can be used for the identification of neutral fragments of OH and H<sub>2</sub>O, HCN, NO and HCl, respectively.</p></div>\",\"PeriodicalId\":13998,\"journal\":{\"name\":\"International Journal of Mass Spectrometry and Ion Physics\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1983-09-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0020-7381(83)85042-6\",\"citationCount\":\"4\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Mass Spectrometry and Ion Physics\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0020738183850426\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Mass Spectrometry and Ion Physics","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0020738183850426","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Electron-impact luminescence spectra and neutral fragments: Identification of neutral fragments by use of fragment emissions
Electron-impact luminescence spectra were measured for cyclohexanol, acetic acid, pyridine, pyrimidine, benzonitrile, aniline, nitrobenzene, p-methoxy-nitrobenzene, 1-chlorobutane, 1-chloropentane, tetrahydrofuran and anisole. The spectra were analyzed and compared with the literature data of mass spectrometry. It was found that fragment emissions of OH(A2Σ+-X2Π), CN(B2Σ-X2Σ), NO(B2Π-X2Π) and HCl+(A2Σ-X2Π) can be used for the identification of neutral fragments of OH and H2O, HCN, NO and HCl, respectively.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
